北京科技大学学报
北京科技大學學報
북경과기대학학보
JOURNAL OF UNIVERSITY OF SCIENCE AND TECHNOLOGY BEIJING
2014年
6期
736-742
,共7页
硅酸盐矿物%蒸压%反应活性%托贝莫来石%尾矿处理
硅痠鹽礦物%蒸壓%反應活性%託貝莫來石%尾礦處理
규산염광물%증압%반응활성%탁패막래석%미광처리
silicate minerals%autoclaving%reaction activity%tobermorite%tailings disposal
为研究尾矿中硅酸盐矿物在蒸压建筑材料体系中的作用,通过 X 射线衍射、热重、扫描电子显微镜、能谱分析和红外光谱分析,对角闪石、拉长石、钠长石和黑云母的蒸压反应活性进行了探讨。结果表明:在180℃蒸压8 h 的条件下,拉长石和钠长石具有蒸压反应活性,角闪石和黑云母不具有蒸压反应活性;拉长石的蒸压产物有水钙铝榴石和斜托贝莫来石,钠长石的蒸压产物有托贝莫来石,蒸压产物相互连接有助于提高结构致密性;反应生成的托贝莫来石矿物均含有 Na,具有一定的固碱作用。
為研究尾礦中硅痠鹽礦物在蒸壓建築材料體繫中的作用,通過 X 射線衍射、熱重、掃描電子顯微鏡、能譜分析和紅外光譜分析,對角閃石、拉長石、鈉長石和黑雲母的蒸壓反應活性進行瞭探討。結果錶明:在180℃蒸壓8 h 的條件下,拉長石和鈉長石具有蒸壓反應活性,角閃石和黑雲母不具有蒸壓反應活性;拉長石的蒸壓產物有水鈣鋁榴石和斜託貝莫來石,鈉長石的蒸壓產物有託貝莫來石,蒸壓產物相互連接有助于提高結構緻密性;反應生成的託貝莫來石礦物均含有 Na,具有一定的固堿作用。
위연구미광중규산염광물재증압건축재료체계중적작용,통과 X 사선연사、열중、소묘전자현미경、능보분석화홍외광보분석,대각섬석、랍장석、납장석화흑운모적증압반응활성진행료탐토。결과표명:재180℃증압8 h 적조건하,랍장석화납장석구유증압반응활성,각섬석화흑운모불구유증압반응활성;랍장석적증압산물유수개려류석화사탁패막래석,납장석적증압산물유탁패막래석,증압산물상호련접유조우제고결구치밀성;반응생성적탁패막래석광물균함유 Na,구유일정적고감작용。
To study the effect of silicate minerals in tailings on autoclaving construction materials, the autoclaving reaction activity of hornblende, labradorite, albite, and biotite was analyzed by X-ray diffraction, thermogravimetry, scanning electron microscopy, energy dispersive X-ray spectroscopy, and infrared spectrometry. The results show that at 180 ℃ for 8 h, labradorite and albite have autoclaving reaction activity, but hornblende and biotite do not. Autoclaving products in the labradorite system contain hibschite and clinotobermorite, while in the albite system contain tobermorite. These products connect together, which helps to improve structural compactness. Na exists in tobermorite minerals, indicating that the minerals have the function of alkali binding.