石油钻采工艺
石油鑽採工藝
석유찬채공예
OIL DRILLING & PRODUCTION TECHNOLOGY
2014年
3期
87-91
,共5页
赖南君%闻一平%傅波%徐俊芳%王思遥%王爱香
賴南君%聞一平%傅波%徐俊芳%王思遙%王愛香
뢰남군%문일평%부파%서준방%왕사요%왕애향
弱凝胶%复合交联%成胶性能%调驱
弱凝膠%複閤交聯%成膠性能%調驅
약응효%복합교련%성효성능%조구
weak gel%composite cross-linking%gelling property%proifle controlling and lfooding
由于弱凝胶调驱体系抗剪切性能弱而限制了其在油藏中的应用,以共聚物丙烯酰胺/丙烯酸/N-乙烯基吡咯烷酮为主剂,加入甲醛-苯酚复合交联剂和高温稳定剂,制备了调驱性能较好的弱凝胶体系。考察了聚合物质量浓度、稳定剂质量浓度、交联剂/聚合物质量比、交联剂配制摩尔比、温度、pH值以及矿化度对成胶性能的影响。确定了弱凝胶体系的最佳使用条件:聚合物AM/AA/NVP质量浓度2000 mg/L,交联剂/聚合物质量比2/1000,交联剂(甲醛/苯酚)摩尔比4∶1,稳定剂(硫脲)质量浓度100 mg/L,pH值为7,温度60℃。室内调驱性能评价表明,该体系具有良好的抗剪切性能,黏度保留率达到91.38%,同时封堵率在99%以上,突破压力大于7 MPa,并且还具有一定的选择封堵能力,剖面改善率达到80%以上。
由于弱凝膠調驅體繫抗剪切性能弱而限製瞭其在油藏中的應用,以共聚物丙烯酰胺/丙烯痠/N-乙烯基吡咯烷酮為主劑,加入甲醛-苯酚複閤交聯劑和高溫穩定劑,製備瞭調驅性能較好的弱凝膠體繫。攷察瞭聚閤物質量濃度、穩定劑質量濃度、交聯劑/聚閤物質量比、交聯劑配製摩爾比、溫度、pH值以及礦化度對成膠性能的影響。確定瞭弱凝膠體繫的最佳使用條件:聚閤物AM/AA/NVP質量濃度2000 mg/L,交聯劑/聚閤物質量比2/1000,交聯劑(甲醛/苯酚)摩爾比4∶1,穩定劑(硫脲)質量濃度100 mg/L,pH值為7,溫度60℃。室內調驅性能評價錶明,該體繫具有良好的抗剪切性能,黏度保留率達到91.38%,同時封堵率在99%以上,突破壓力大于7 MPa,併且還具有一定的選擇封堵能力,剖麵改善率達到80%以上。
유우약응효조구체계항전절성능약이한제료기재유장중적응용,이공취물병희선알/병희산/N-을희기필각완동위주제,가입갑철-분분복합교련제화고온은정제,제비료조구성능교호적약응효체계。고찰료취합물질량농도、은정제질량농도、교련제/취합물질량비、교련제배제마이비、온도、pH치이급광화도대성효성능적영향。학정료약응효체계적최가사용조건:취합물AM/AA/NVP질량농도2000 mg/L,교련제/취합물질량비2/1000,교련제(갑철/분분)마이비4∶1,은정제(류뇨)질량농도100 mg/L,pH치위7,온도60℃。실내조구성능평개표명,해체계구유량호적항전절성능,점도보류솔체도91.38%,동시봉도솔재99%이상,돌파압력대우7 MPa,병차환구유일정적선택봉도능력,부면개선솔체도80%이상。
The weak shear resistance of weak gel proifle controlling and lfooding system limits its application in reservoirs, we prepared a weak gel system with favorable proifle controlling and lfooding performance with AM/AA/NVP as the main agent and added Phenol-formaldehyde as cross-linking agent and temperature stabilizer. We studied the effects of polymer concentration, stabilizer con-centration, crosslinker/polymer proportion, crosslinker concentration, temperature, pH and salinity on the gelling property. The optimum conditions for preparing the weak gel system were identiifed as follows:concentration of polymer (AM/AA/NVP):2 000 mg/L;mass ratio of crosslinker/polymer:2/1 000;proportion of crosslinker (formaldehyde/phenol):4∶1;concentration of stabilizer:100 mg/L;pH of the system:7;and suitable temperature 60℃. The in-house evaluation on proifle controlling and lfooding performance shows that the system has good shear resistance, its viscosity retention rate is up to 91.38%, and its plugging rate is above 99%, its breakthrough pres-sure is greater than 7 MPa and has certain selective plugging capability, and the sectional improvement rate is over 80%.