广州化工
廣州化工
엄주화공
GUANGZHOU CHEMICAL INDUSTRY AND TECHNOLOGY
2014年
13期
59-60,63
,共3页
徐娟%蔡李鹏%田瑶%曾敏%范玉桥%王娟
徐娟%蔡李鵬%田瑤%曾敏%範玉橋%王娟
서연%채리붕%전요%증민%범옥교%왕연
对苯二甲酸%钕%配合物%电化学
對苯二甲痠%釹%配閤物%電化學
대분이갑산%녀%배합물%전화학
neodymium%terephthalicacid%complex%electrochemical properties
水热法合成了以对苯二甲酸和柠檬酸为配体的钕的配合物。通过红外、紫外、荧光、循环伏安法、热重分析对其进行了表征。结果表明,配合物在372 nm处具有较强的荧光发射峰,在-0.3~0.4 V的电势范围内研究配合物的电化学性质,研究结果表明,配合物在此电势范围内具有电化学活性。
水熱法閤成瞭以對苯二甲痠和檸檬痠為配體的釹的配閤物。通過紅外、紫外、熒光、循環伏安法、熱重分析對其進行瞭錶徵。結果錶明,配閤物在372 nm處具有較彊的熒光髮射峰,在-0.3~0.4 V的電勢範圍內研究配閤物的電化學性質,研究結果錶明,配閤物在此電勢範圍內具有電化學活性。
수열법합성료이대분이갑산화저몽산위배체적녀적배합물。통과홍외、자외、형광、순배복안법、열중분석대기진행료표정。결과표명,배합물재372 nm처구유교강적형광발사봉,재-0.3~0.4 V적전세범위내연구배합물적전화학성질,연구결과표명,배합물재차전세범위내구유전화학활성。
The research of a novel neodymium (Ⅲ) complex synthesized with terephthalic acid and citric acid as ligands by hydrothermal method was introduced.According to the infrared , ultraviolet , fluorescence and cyclic voltammetry, thermogravimetric analysis on the characterization , the results indicated that the complex had strong fluorescence emission peak at 372.0 nm.In the potential range of -0.3 ~0.4 V, electrochemical properties of the complex were researched , and it showed obvious electrochemical activity within the scope of this potential.