西南林业大学学报
西南林業大學學報
서남임업대학학보
JOURNAL OF SOUTHWEST FORESTRY COLLEGE
2014年
3期
89-94
,共6页
轻木%改性剂%化学改性%木材性能%红外光谱图
輕木%改性劑%化學改性%木材性能%紅外光譜圖
경목%개성제%화학개성%목재성능%홍외광보도
balsa wood%modifiers%chemical modification%properties of wood%infrared spectrogram
以人工林轻木为研究对象,采用酚醛树脂和壳聚糖2种不同功能类型的改性剂对试件进行改性处理,并用傅立叶变换红外光谱仪、X射线衍射仪对改性前后木材的相关性能进行表征,分析改性前后木材性能的变化。结果表明,PF树脂改性后,轻木的抗胀率和阻湿率达到30%左右,端面硬度、径面硬度和顺纹抗压强度分别提高29.7%,25.0%,50.0%;单位质量的壳聚糖对轻木力学性能的贡献是PF树脂的4~8倍。红外光谱图表明,改性剂与木材内部基团发生交联反应。X射线衍射仪测试表明,木材改性剂使木材结晶区域宽度均增加约0.2 nm,其中PF处理后轻木的相对结晶度提高4.0%,而壳聚糖处理后的轻木相对结晶度提高约12.2%。
以人工林輕木為研究對象,採用酚醛樹脂和殼聚糖2種不同功能類型的改性劑對試件進行改性處理,併用傅立葉變換紅外光譜儀、X射線衍射儀對改性前後木材的相關性能進行錶徵,分析改性前後木材性能的變化。結果錶明,PF樹脂改性後,輕木的抗脹率和阻濕率達到30%左右,耑麵硬度、徑麵硬度和順紋抗壓彊度分彆提高29.7%,25.0%,50.0%;單位質量的殼聚糖對輕木力學性能的貢獻是PF樹脂的4~8倍。紅外光譜圖錶明,改性劑與木材內部基糰髮生交聯反應。X射線衍射儀測試錶明,木材改性劑使木材結晶區域寬度均增加約0.2 nm,其中PF處理後輕木的相對結晶度提高4.0%,而殼聚糖處理後的輕木相對結晶度提高約12.2%。
이인공림경목위연구대상,채용분철수지화각취당2충불동공능류형적개성제대시건진행개성처리,병용부립협변환홍외광보의、X사선연사의대개성전후목재적상관성능진행표정,분석개성전후목재성능적변화。결과표명,PF수지개성후,경목적항창솔화조습솔체도30%좌우,단면경도、경면경도화순문항압강도분별제고29.7%,25.0%,50.0%;단위질량적각취당대경목역학성능적공헌시PF수지적4~8배。홍외광보도표명,개성제여목재내부기단발생교련반응。X사선연사의측시표명,목재개성제사목재결정구역관도균증가약0.2 nm,기중PF처리후경목적상대결정도제고4.0%,이각취당처리후적경목상대결정도제고약12.2%。
Modification treatment of balsa wood was conducted through 2 wood modifiers of phenol-formalde-hyde resin and chitosan,and compared the characteristics of the treated and untreated wood with X-ray diffractome-ter (XRD),and Fourier transform infrared (FTIR)spectrophotometer.Results indicated that the ASE and MEE reached around 30%,and the surface hardness and compressive strength parallel grain of the treated wood in-creased by about 29.7%,25.0% and 50.0% after PF impregnation,respectively.The chitosan had the better effect of modification than PF because the chitosan had the 4-8 times increments on physical properties of wood than PF.The FTIR and XRD spectra test showed that there was cross-linking reaction between the modifier and the internal parts of the wood.And the modifier could increase the width of crystal region about 0.2 nm,and the rela-tive crystallinity of balsa wood was increased by 4.0%after PF treatment.Moreover,chitosan had an obvious effect on the relative crystallinity of balsa wood,increasing it about 12.2%.