稀土学报(英文版)
稀土學報(英文版)
희토학보(영문판)
JOURNAL OF RARE EARTHS
2014年
7期
655-662
,共8页
杜成梅%马君%姚路%陈国坚%杨通晗%曾维敬%何维
杜成梅%馬君%姚路%陳國堅%楊通晗%曾維敬%何維
두성매%마군%요로%진국견%양통함%증유경%하유
Dy-Fe-Mn%phase diagram%crystal structure%X-ray diffraction%rare earths
Rare-earth intermetallic compounds formed in many R-Fe-Mn (R=rare-earth element) systems exhibit excellent properties. In order to understand the existence and stability of the compounds in the system and further search for the potential application of R-Fe-Mn alloys in various aspects, it is necessary to investigate the phase relations of the Dy-Fe-Mn ternary system. A total of 96 samples of the Dy-Fe-Mn alloys were prepared by arc-melting and examined by metallographic analysis, X-ray diffraction (XRD), scanning electron microscopy (SEM) and energy dispersive spectroscopy (EDS) techniques. The phase relationship of the Dy-Fe-Mn system at 773 K was determined. It was found that the isothermal section was characterized by intermediate solid solutions based on the substitutions of Fe/Mn atoms and the large extensions of the binaries into the ternary domains. The solid solubilities of the third ele-ment in the binary compounds and the phase boundaries were also determined by XRD technique using the phase disappearing method combined with the lattice parameter method and SEM/EDS technique. Two pairs of corresponding binary compounds in the Dy-Fe and Dy-Mn systems (DyFe2 and DyMn2, Dy6Fe23 and Dy6Mn23) formed a continuous series of solid solution at 773 K, respectively.