CAJ | 학술논문

石油开采及冶炼废水中的环烷酸进入水环境中将严重影响水环境质量，对水生生物造成毒害，准确快速地检测其含量可为其监控提供基础数据。本研究利用固相萃取（ SPE）法从水中萃取环烷酸，并利用气相色谱-质谱联用法（ GC-MS）对样品中的环烷酸进行定量定性检测。结果表明本检测方法对浓度在10～30 mg／L范围内的环己基甲酸、环己基乙酸、环己基丙酸、环己基丁酸的回收率在80％～120％之间。环烷酸水溶液的pH值对其回收率影响较小，酸性条件下的环烷酸回收率几乎无改变，碱性条件下的环烷酸回收率略有降低。
석유개채급야련폐수중적배완산진입수배경중장엄중영향수배경질량，대수생생물조성독해，준학쾌속지검측기함량가위기감공제공기출수거。본연구이용고상췌취（ SPE）법종수중췌취배완산，병이용기상색보-질보련용법（ GC-MS）대양품중적배완산진행정량정성검측。결과표명본검측방법대농도재10～30 mg／L범위내적배기기갑산、배기기을산、배기기병산、배기기정산적회수솔재80％～120％지간。배완산수용액적pH치대기회수솔영향교소，산성조건하적배완산회수솔궤호무개변，감성조건하적배완산회수솔략유강저。
Naphthenic acids ( NAs) in produced water and petrochemical wastewater issuing into water environment had negative influence on water quality and aquatic lives , thus it was necessary to develop methods to detect NAs.This research employed solid phase extraction (SPE) and gas chromatography -mass spectrometer (GC-MS) to analyze NAs in water quantitatively and qualitatively.The results indicated that the recoveries for 4 model NAs-cyclohexanecarboxylic acid, cyclohexaneacetic acid , cyclohecanepropanoic acid and cyclohexanebutanoic acid in the concentration range of 10~30 mg/L were 80%~120%.pH of the water had little impact on NAs recovery.NAs recovery under acid condition had almost no change , and under basic condition its recovery declined slightly.