广州化工
廣州化工
엄주화공
GUANGZHOU CHEMICAL INDUSTRY AND TECHNOLOGY
2014年
12期
60-62,66
,共4页
曾彪%曹光龙%宋亚%赵宇澄%张晓梅
曾彪%曹光龍%宋亞%趙宇澄%張曉梅
증표%조광룡%송아%조우징%장효매
聚氨酯注浆材料%无机盐%固化温度%阻燃性能%表面电阻
聚氨酯註漿材料%無機鹽%固化溫度%阻燃性能%錶麵電阻
취안지주장재료%무궤염%고화온도%조연성능%표면전조
polyurethane grouting material%inorganic salt%curing temperature%flame resistance%surface resistance
研究了无机钠盐和镁盐对聚氨酯注浆材料固化过程温度的影响,并研究了添加无机盐对材料阻燃性能、表面电阻及抗压强度的影响。结果表明,环境温度为35℃,添加聚醚组分1.2%(质量百分比)无机盐,注浆材料固化最高温度有不同程度下降。其中,添加MgCl2时,注浆材料固化最高温度为102℃,与空白相比,下降了25℃。添加无机盐后,材料阻燃性能略有提高,表面电阻基本不变;抗压强度有所降低。热重分析表明,添加MgCl2时材料的热稳定性无明显改变,而添加其它无机盐,热稳定性有不同程度降低。
研究瞭無機鈉鹽和鎂鹽對聚氨酯註漿材料固化過程溫度的影響,併研究瞭添加無機鹽對材料阻燃性能、錶麵電阻及抗壓彊度的影響。結果錶明,環境溫度為35℃,添加聚醚組分1.2%(質量百分比)無機鹽,註漿材料固化最高溫度有不同程度下降。其中,添加MgCl2時,註漿材料固化最高溫度為102℃,與空白相比,下降瞭25℃。添加無機鹽後,材料阻燃性能略有提高,錶麵電阻基本不變;抗壓彊度有所降低。熱重分析錶明,添加MgCl2時材料的熱穩定性無明顯改變,而添加其它無機鹽,熱穩定性有不同程度降低。
연구료무궤납염화미염대취안지주장재료고화과정온도적영향,병연구료첨가무궤염대재료조연성능、표면전조급항압강도적영향。결과표명,배경온도위35℃,첨가취미조분1.2%(질량백분비)무궤염,주장재료고화최고온도유불동정도하강。기중,첨가MgCl2시,주장재료고화최고온도위102℃,여공백상비,하강료25℃。첨가무궤염후,재료조연성능략유제고,표면전조기본불변;항압강도유소강저。열중분석표명,첨가MgCl2시재료적열은정성무명현개변,이첨가기타무궤염,열은정성유불동정도강저。
The effects of inorganic sodium and magnesium salts on curing temperature of polyurethane grouting material were investigated , and the effects of those salts on material properties including flame resistance , surface resistance and compression strength were studied.Results showed that the maximum curing temperatures decreased in varying extent at ambient temperature 35 ℃after 1.2% ( mass percentage ) of studied inorganic salts based on polyether polyalcohol component were added into polyurethane grouting material.Among them, when MgCl2 was added, the maximum curing temperature decreased 25 ℃ in comparison with control , to reach 102 ℃.Adding inorganic salts , a slight increase in flame retardant property of the material was observed , almost no change in surface resistance , and a decrease in compressive strength was observed also.Thermal gravimetric analysis displayed that the thermal stability of the material blending MgCl 2 exhibited no obvious change , while the material blending the other studied inorganic salts reduced in varying degrees.