功能材料
功能材料
공능재료
JOURNAL OF FUNCTIONAL MATERIALS
2014年
12期
12128-12131
,共4页
刘长友%王金芳%孙晓燕%介万奇
劉長友%王金芳%孫曉燕%介萬奇
류장우%왕금방%손효연%개만기
硒化锌%生长机理%牺牲模板法%氧化锌
硒化鋅%生長機理%犧牲模闆法%氧化鋅
서화자%생장궤리%희생모판법%양화자
ZnSe%growth mechanism%sacrificial temple route%ZnO
采用牺牲Zn基片上ZnO 纳米柱模板技术,以三乙醇胺(TEA)为溶剂,以 HSe-离子为硒源,在150℃恒温8 h 制备了 ZnSe 亚微米管。采用 FE-SEM、EDS、XRD、TEM 及SAED手段对样品的形貌、结构及成分进行了表征。结果表明,多晶管状ZnSe的直径为150 nm左右,且具有封口、规则开口、不规则开口以及呈半管状,管壁由直径约30~40 nm 左右的颗粒组成。据此形貌特征,依负离子多面体生长基元模型,分析了ZnSe亚微米管的形成机制。
採用犧牲Zn基片上ZnO 納米柱模闆技術,以三乙醇胺(TEA)為溶劑,以 HSe-離子為硒源,在150℃恆溫8 h 製備瞭 ZnSe 亞微米管。採用 FE-SEM、EDS、XRD、TEM 及SAED手段對樣品的形貌、結構及成分進行瞭錶徵。結果錶明,多晶管狀ZnSe的直徑為150 nm左右,且具有封口、規則開口、不規則開口以及呈半管狀,管壁由直徑約30~40 nm 左右的顆粒組成。據此形貌特徵,依負離子多麵體生長基元模型,分析瞭ZnSe亞微米管的形成機製。
채용희생Zn기편상ZnO 납미주모판기술,이삼을순알(TEA)위용제,이 HSe-리자위서원,재150℃항온8 h 제비료 ZnSe 아미미관。채용 FE-SEM、EDS、XRD、TEM 급SAED수단대양품적형모、결구급성분진행료표정。결과표명,다정관상ZnSe적직경위150 nm좌우,차구유봉구、규칙개구、불규칙개구이급정반관상,관벽유직경약30~40 nm 좌우적과립조성。거차형모특정,의부리자다면체생장기원모형,분석료ZnSe아미미관적형성궤제。
Polycrystalline ZnSe submicro-tubes on the zinc substrate were fabricated via the sacrificial zinc oxide temple route in HSe- ion solution of TEA at 150 ℃ for 8 h.The structures and morphologies of as-synthesized samples were characterized by FE-SEM,EDS,XRD,TEM and SAED.The average diameter of ZnSe tubes was 100-150 nm with the closed ends,the regular open ends,irregular open ends,and even the semi-tube ends. The wall of submicro-tubes consists of the particles with the diameter of 30-40 nm.According to the growth unit model of anion coordination polyhedron,the formation mechanism of ZnSe submicro-tubes was suggested.