CAJ | 학술논문

综述了基于聚合反应机理、面向聚合物链结构的聚合反应过程模型化方法。分别介绍了聚合物分子量及其分布、共聚物组成以及序列结构分布的模型，回顾比较了各模型发展历程与应用。指出在规模化聚合物生产过程中面向链结构建模的重要性，面向序列结构分布建模是烯烃聚合反应过程模型化领域的重要发展方向。
종술료기우취합반응궤리、면향취합물련결구적취합반응과정모형화방법。분별개소료취합물분자량급기분포、공취물조성이급서렬결구분포적모형，회고비교료각모형발전역정여응용。지출재규모화취합물생산과정중면향련결구건모적중요성，면향서렬결구분포건모시희경취합반응과정모형화영역적중요발전방향。
In this review, modeling of olefin polymerization process based on polymerization mechanism for the polymer chain structure was surveyed. Developments and applications of the models for molecular weight and its distribution, copolymer composition as well as sequence distribution in polymerization process were reviewed. The importance of chain-structure modeling was emphasized and the modeling of the sequence structure distribution of copolymers was suggested as a future direction of research in olefin polymerization.