CAJ | 학술논문

【目的】研究红树白骨壤（Avicenniamavina ）果实中芳香酯类化合物。【方法】采用柱色谱、凝胶层析和高效液相色谱分离技术，从白骨壤果实中分离芳香酯类单体化合物，运用理化和波谱分析方法鉴定其化学结构。【结果】从白骨壤果实中分离获得7个芳香酯类化合物，分别鉴定为甲基（4-氯-4[N-羟氨基]苯基）醋酸酯（1）、4-（2-羟基乙氧基）苯甲酸甲酯（2）、邻苯二甲酸二异丙酯（3）、咖啡酸甲酯（4）、原儿茶酸甲酯（5）、邻苯二甲酸二（2-乙基）己酯（6）、邻苯二甲酸二丁酯（7）。【结论】化合物1～7均是首次从该种海洋植物中分离得到，其中化合物1和2为新天然产物。
【목적】연구홍수백골양（Avicenniamavina ）과실중방향지류화합물。【방법】채용주색보、응효층석화고효액상색보분리기술，종백골양과실중분리방향지류단체화합물，운용이화화파보분석방법감정기화학결구。【결과】종백골양과실중분리획득7개방향지류화합물，분별감정위갑기（4-록-4[N-간안기]분기）작산지（1）、4-（2-간기을양기）분갑산갑지（2）、린분이갑산이이병지（3）、가배산갑지（4）、원인다산갑지（5）、린분이갑산이（2-을기）기지（6）、린분이갑산이정지（7）。【결론】화합물1～7균시수차종해충해양식물중분리득도，기중화합물1화2위신천연산물。
Abstruct:[Objective]The chemical constituents were investigated from the fruits of Mangrove Avicennia marina .[Methods]The compounds were isolated and purified by column chroma-tography,gel chromatography and HPLC,and their structures were identified by spectral ana-lyses.[Results]Seven aromatic esters (1~7)were isolated from MangroveAvicennia marina . Their structures were identified as Methyl (4-chloro-4[N-hydroxyamino]phenyl)acetate (1), Methyl 4-(2-Hydroxyethoxy)benzoate (2),Diisopropyl phthalate (3),Methyl caffeate (4), Protocatechuic acid methyl ester (5),Di-(2-ethylhexyl)phthalate (6),Dibutyl phthalate (7)on the basis of extensive spectroscopic analysis.[Conclusion]Compounds 1~7 were isolated from the marine plant for the first time,and compounds 1 and 2 were new natural compouds.