石油与天然气化工
石油與天然氣化工
석유여천연기화공
CHEMICAL ENGINEERING OF OIL AND GAS
2014年
3期
326-330
,共5页
杜文婷%王兵%刘光全%任雯%刘鹏%任宏洋
杜文婷%王兵%劉光全%任雯%劉鵬%任宏洋
두문정%왕병%류광전%임문%류붕%임굉양
炼油废水%低温多效蒸发%混凝剂%脱硅除浊度
煉油廢水%低溫多效蒸髮%混凝劑%脫硅除濁度
련유폐수%저온다효증발%혼응제%탈규제탁도
oil refinery effluent%low temperature multi-effect evaporation%coagulation%sili-con and turbidity removal
炼油厂污水经A2/O为核心的生化系统处理后,水质可达到污水综合排放标准。有效利用炼油厂低温余热,通过负压多效蒸发工艺实现净化后污水的回收再利用,是炼油厂节能减排的新举措。进水水质中硅、浊度是蒸发工艺防垢、控制水质的主要参数,以硅、浊度的同步去除为目标,研究了石灰、镁盐沉淀、铁铝盐共沉淀法对硅和浊度去除效果的影响。结果表明,当Ca (OH )2的投加量为500 m g/L时,硅、浊度的同步去除率分别为79.2%和4.2%;p H值=10.0,Mg Cl2投加量为400 mg/L时,硅、浊度的同步去除率分别为91.6%和74.4%;优选的Fe(Ⅱ/Ⅲ)Al复合混凝剂投加量为400 mg/L时,硅、浊度的同步去除率分别为91.9%和90.4%。Fe(Ⅱ/Ⅲ)Al复合混凝剂作用效果满足蒸发系统对进水硅和浊度的控制要求,处理后硅含量为17.93 m g/L ,浊度为3 NTU。
煉油廠汙水經A2/O為覈心的生化繫統處理後,水質可達到汙水綜閤排放標準。有效利用煉油廠低溫餘熱,通過負壓多效蒸髮工藝實現淨化後汙水的迴收再利用,是煉油廠節能減排的新舉措。進水水質中硅、濁度是蒸髮工藝防垢、控製水質的主要參數,以硅、濁度的同步去除為目標,研究瞭石灰、鎂鹽沉澱、鐵鋁鹽共沉澱法對硅和濁度去除效果的影響。結果錶明,噹Ca (OH )2的投加量為500 m g/L時,硅、濁度的同步去除率分彆為79.2%和4.2%;p H值=10.0,Mg Cl2投加量為400 mg/L時,硅、濁度的同步去除率分彆為91.6%和74.4%;優選的Fe(Ⅱ/Ⅲ)Al複閤混凝劑投加量為400 mg/L時,硅、濁度的同步去除率分彆為91.9%和90.4%。Fe(Ⅱ/Ⅲ)Al複閤混凝劑作用效果滿足蒸髮繫統對進水硅和濁度的控製要求,處理後硅含量為17.93 m g/L ,濁度為3 NTU。
련유엄오수경A2/O위핵심적생화계통처리후,수질가체도오수종합배방표준。유효이용련유엄저온여열,통과부압다효증발공예실현정화후오수적회수재이용,시련유엄절능감배적신거조。진수수질중규、탁도시증발공예방구、공제수질적주요삼수,이규、탁도적동보거제위목표,연구료석회、미염침정、철려염공침정법대규화탁도거제효과적영향。결과표명,당Ca (OH )2적투가량위500 m g/L시,규、탁도적동보거제솔분별위79.2%화4.2%;p H치=10.0,Mg Cl2투가량위400 mg/L시,규、탁도적동보거제솔분별위91.6%화74.4%;우선적Fe(Ⅱ/Ⅲ)Al복합혼응제투가량위400 mg/L시,규、탁도적동보거제솔분별위91.9%화90.4%。Fe(Ⅱ/Ⅲ)Al복합혼응제작용효과만족증발계통대진수규화탁도적공제요구,처리후규함량위17.93 m g/L ,탁도위3 NTU。
The oil refinery effluent was dealt with biochemical treatment taking A 2/O as a core ,and its quality could reach the comprehensive discharge standard of effluent .The effluent could be recycled by the low pressure multi-effect evaporation system using the low temperature heat of oil refinery ,and it was the new measure of energy saving and emission reduction .The sil-icon and turbidity were the main parameters of evaporation process .The removal effect of silicon and turbidity by softening with lime ,magnesium salt precipitation and precipitation by combina-tion coagulant of molysite and aluminium salt were researched .The results indicated that :when the dosage of Ca(OH)2 was 500 mg/L ,the removal rate of silicon and turbidity were 79 .2% and 4 .2% ,respectively ,and when the dosage of MgCl2 was 400 mg/L at the pH value of 10 ,the re-moval rate of silicon and turbidity were 91 .6% and 74 .4% ,respectively .The requirement of low temperature multi-effect evaporation system could be achieved ,w hen the dosage of Fe(Ⅱ/Ⅲ)Al combination coagulant was 400 mg/L and the removal rate of silicon and turbidity were 91 .9%and 90 .4% ,respectively . The residual silicon content and turbidity were 17 .93 mg/L and 3 NTU .