昆明学院学报
昆明學院學報
곤명학원학보
JOURNAL OF KUNMING UNIVERSITY
2014年
3期
72-74
,共3页
白文莉%刘奕麟%郭文婷%曾剑平
白文莉%劉奕麟%郭文婷%曾劍平
백문리%류혁린%곽문정%증검평
环已基氨基磺酸钠%甜蜜素%气相色谱法%内标法%饮料
環已基氨基磺痠鈉%甜蜜素%氣相色譜法%內標法%飲料
배이기안기광산납%첨밀소%기상색보법%내표법%음료
sodium n-cyclohexylsulfamate%sodium cyclamateresidues%GC%internal standard method%beverage
使用柱前衍生化对饮料中的环已基氨基磺酸钠进行处理，用含内标的正己烷萃取衍生化产物，以GC-FID测定其质量分数．结果表明：环已基氨基磺酸钠质量浓度在0.05～5.00 mg/mL范围内，与峰面积线性关系良好（r＝0.9999）；检出限（S/N＝3∶1）为0.95 mg/kg，定量限（S/N＝10∶1）为4.75 mg/kg；平均回收率为96.0％， RSD为2.3％．该方法重复性好，适合饮料中环已基氨基磺酸钠的检测．
使用柱前衍生化對飲料中的環已基氨基磺痠鈉進行處理，用含內標的正己烷萃取衍生化產物，以GC-FID測定其質量分數．結果錶明：環已基氨基磺痠鈉質量濃度在0.05～5.00 mg/mL範圍內，與峰麵積線性關繫良好（r＝0.9999）；檢齣限（S/N＝3∶1）為0.95 mg/kg，定量限（S/N＝10∶1）為4.75 mg/kg；平均迴收率為96.0％， RSD為2.3％．該方法重複性好，適閤飲料中環已基氨基磺痠鈉的檢測．
사용주전연생화대음료중적배이기안기광산납진행처리，용함내표적정기완췌취연생화산물，이GC-FID측정기질량분수．결과표명：배이기안기광산납질량농도재0.05～5.00 mg/mL범위내，여봉면적선성관계량호（r＝0.9999）；검출한（S/N＝3∶1）위0.95 mg/kg，정량한（S/N＝10∶1）위4.75 mg/kg；평균회수솔위96.0％， RSD위2.3％．해방법중복성호，괄합음료중배이기안기광산납적검측．
Using the method of column deriving disposes sodium N-cyclohexylsulfamate in beverages to extract the derivant by the GC internal standard method and measure the mass fraction by GC-FID. The result showed that the mass concentration of sodium N-cyclo-hexylsulfamate is in the range of 0.05-5.00 mg/mL in positive relationship with peak area linear (r =0.999 9 );the LOD was 0.95 g/kg and the LOQ was 4.75 mg/kg.The extraction recovery was 96.0%and the RSD was 2.3%.This method is good at repro-ducibility and adaptive to inspect sodium N-cyclohexylsulfamate in beverages.
