东南大学学报(自然科学版)
東南大學學報(自然科學版)
동남대학학보(자연과학판)
JOURNAL OF SOUTHEAST UNIVERSITY
2014年
5期
1068-1071
,共4页
张久鹏%杜慧%裴建中%徐士翠
張久鵬%杜慧%裴建中%徐士翠
장구붕%두혜%배건중%서사취
温拌沥青%老化动力学%正戊烷沥青质%反应速率常数%反应活化能
溫拌瀝青%老化動力學%正戊烷瀝青質%反應速率常數%反應活化能
온반력청%노화동역학%정무완력청질%반응속솔상수%반응활화능
warm mix asphalt%aging kinetics%n-pentane asphaltene%reaction constant%reaction ac-tivation energy
在不同老化温度和老化时间下,对温拌沥青、基质沥青进行了老化试验,测试了老化前后沥青中正戊烷沥青质含量,建立了以正戊烷沥青质含量为参数的老化动力学模型,计算了老化反应速率常数和老化反应活化能等参数,据此对比研究了温拌沥青与基质沥青的老化动力特性。研究结果表明:沥青老化遵循一级反应动力学方程,老化过程中正戊烷沥青质含量均随时间的延长和温度的升高而增大,而温拌沥青具有较低的反应速率常数和较高的反应活化能,因此抗老化性能更好。以正戊烷沥青质含量为参数的老化动力学方程,能够较好地区分温拌沥青与基质沥青老化过程的差异。
在不同老化溫度和老化時間下,對溫拌瀝青、基質瀝青進行瞭老化試驗,測試瞭老化前後瀝青中正戊烷瀝青質含量,建立瞭以正戊烷瀝青質含量為參數的老化動力學模型,計算瞭老化反應速率常數和老化反應活化能等參數,據此對比研究瞭溫拌瀝青與基質瀝青的老化動力特性。研究結果錶明:瀝青老化遵循一級反應動力學方程,老化過程中正戊烷瀝青質含量均隨時間的延長和溫度的升高而增大,而溫拌瀝青具有較低的反應速率常數和較高的反應活化能,因此抗老化性能更好。以正戊烷瀝青質含量為參數的老化動力學方程,能夠較好地區分溫拌瀝青與基質瀝青老化過程的差異。
재불동노화온도화노화시간하,대온반력청、기질력청진행료노화시험,측시료노화전후력청중정무완력청질함량,건립료이정무완력청질함량위삼수적노화동역학모형,계산료노화반응속솔상수화노화반응활화능등삼수,거차대비연구료온반력청여기질력청적노화동력특성。연구결과표명:력청노화준순일급반응동역학방정,노화과정중정무완력청질함량균수시간적연장화온도적승고이증대,이온반력청구유교저적반응속솔상수화교고적반응활화능,인차항노화성능경호。이정무완력청질함량위삼수적노화동역학방정,능구교호지구분온반력청여기질력청노화과정적차이。
The aging tests of warm mix asphalt and matrix asphalt were conducted at different aging temperatures and time,and the contents of n-pentane asphaltene in asphalt were measured before and after aging.By taking the content of n-pentane asphaltene as the parameter,the aging kinetics mod-els were established,and the reaction constants and reaction activation energies were calculated to contrastively analyze the aging kinetics characteristics of warm mix asphalt and matrix asphalt.Re-sults indicate that the aging process of the two asphalts follows the first-order kinetics reaction equa-tion,and the content of n-pentane asphaltene increases with the aging temperature and the aging time.The reaction constant of warm mix asphalt is lower than that of matrix asphalt,but the reaction activation energy of warm mix asphalt is bigger than that of matrix asphalt,so the anti-aging proper-ty of warm mix asphalt is better.The aging kinetics models based on the content of n-pentane as-phaltene can be used to well distinguish the difference of aging processes between warm mix asphalt and matrix asphalt.