东南大学学报(自然科学版)
東南大學學報(自然科學版)
동남대학학보(자연과학판)
JOURNAL OF SOUTHEAST UNIVERSITY
2014年
5期
963-967
,共5页
曹俊%王志飞%钟文琪%金保癉%王恺%陶敏
曹俊%王誌飛%鐘文琪%金保癉%王愷%陶敏
조준%왕지비%종문기%금보단%왕개%도민
中高温%HCl%脱除效率%类水滑石结构吸附剂
中高溫%HCl%脫除效率%類水滑石結構吸附劑
중고온%HCl%탈제효솔%류수활석결구흡부제
medium-high temperature%HCl%removal efficiency%hydrotalcite-like sorbent
为获得中高温条件下高效脱除烟气中HCl的吸附剂,对自制类水滑石吸附剂HTL与常用的吸附剂CaO,NaHCO3在不同温度(300~700℃)、不同HCl初始浓度(750~1500 mg/m3)以及不同反应时间条件下对HCl的脱除特性进行了比较研究。结果表明:随HCl初始浓度的升高、反应时间的延长,CaO,NaHCO3的脱除效率都呈下降趋势;随温度升高,CaO对HCl的脱除效率一直呈下降趋势,而NaHCO3对HCl的脱除效率先下降,在550℃后又呈现上升趋势,并且在温度高于600℃时NaHCO3,CaO均出现了结块和熔融现象;而以上各条件对HTL的影响不大,其脱除效率一直高于95%。
為穫得中高溫條件下高效脫除煙氣中HCl的吸附劑,對自製類水滑石吸附劑HTL與常用的吸附劑CaO,NaHCO3在不同溫度(300~700℃)、不同HCl初始濃度(750~1500 mg/m3)以及不同反應時間條件下對HCl的脫除特性進行瞭比較研究。結果錶明:隨HCl初始濃度的升高、反應時間的延長,CaO,NaHCO3的脫除效率都呈下降趨勢;隨溫度升高,CaO對HCl的脫除效率一直呈下降趨勢,而NaHCO3對HCl的脫除效率先下降,在550℃後又呈現上升趨勢,併且在溫度高于600℃時NaHCO3,CaO均齣現瞭結塊和鎔融現象;而以上各條件對HTL的影響不大,其脫除效率一直高于95%。
위획득중고온조건하고효탈제연기중HCl적흡부제,대자제류수활석흡부제HTL여상용적흡부제CaO,NaHCO3재불동온도(300~700℃)、불동HCl초시농도(750~1500 mg/m3)이급불동반응시간조건하대HCl적탈제특성진행료비교연구。결과표명:수HCl초시농도적승고、반응시간적연장,CaO,NaHCO3적탈제효솔도정하강추세;수온도승고,CaO대HCl적탈제효솔일직정하강추세,이NaHCO3대HCl적탈제효솔선하강,재550℃후우정현상승추세,병차재온도고우600℃시NaHCO3,CaO균출현료결괴화용융현상;이이상각조건대HTL적영향불대,기탈제효솔일직고우95%。
In order to obtain sorbent that can remove HCl with high efficiency at medium-high tem-perature,the removal efficiency of hydrotalcite-like sorbent (HTL)prepared domestically was com-pared with traditional sorbents such as CaO,NaHCO3 under different temperatures (300 to 700 ℃), initial concentrations of HCl (750 to 1 500 mg/m3 ),and reaction times.The results show that,with the increase of initial concentrations of HCl and the extension of reaction time,the removal efficien-cies of CaO,NaHCO3 decrease.With the temperature increasing,the removal efficiency of CaO de-clines.However,the removal efficiency of NaHCO3 falls at the beginning,and then rises after 550℃.And when the temperature is high than 600 ℃,NaHCO3 and CaO are sintered and melted. However,the above conditions have little influence on HTL.The removal efficiency of HTL under different conditions always keeps more than 95%.