功能材料
功能材料
공능재료
JOURNAL OF FUNCTIONAL MATERIALS
2014年
18期
18047-18051
,共5页
李侠%周洪庆%任路超%谢文涛%唐国伟
李俠%週洪慶%任路超%謝文濤%唐國偉
리협%주홍경%임로초%사문도%당국위
流延法%LTCC%硼硅酸盐玻璃%介电性能%微观结构
流延法%LTCC%硼硅痠鹽玻璃%介電性能%微觀結構
류연법%LTCC%붕규산염파리%개전성능%미관결구
tape casting%LTCC%borosilicate glass/alumina%dielectric properties%microstructure
借助高效流延成型工艺,探讨了多种溶剂组合与分散剂对玻璃/陶瓷浆料体系流变性能的影响,通过对玻璃/陶瓷料、塑化剂与粘结剂等配制浆料的组成配比进行优化设计,详细研究了浆料中各组成含量对流延生料带体积密度,以及对烧成后玻璃/陶瓷致密度、物相等微观结构与性能的影响。结果表明,适当的浆料组成类型及含量对提高试样的烧成致密度、降低高频介电损耗、改善微观结构均有明显的影响;850℃烧结试样10 MHz测试,相对介电常数为7.7,介电损耗2.0×10-4,25~500℃热膨胀系数(7.30~7.65)×10-6/℃,满足模块级LTCC大面积高密度封装要求。
藉助高效流延成型工藝,探討瞭多種溶劑組閤與分散劑對玻璃/陶瓷漿料體繫流變性能的影響,通過對玻璃/陶瓷料、塑化劑與粘結劑等配製漿料的組成配比進行優化設計,詳細研究瞭漿料中各組成含量對流延生料帶體積密度,以及對燒成後玻璃/陶瓷緻密度、物相等微觀結構與性能的影響。結果錶明,適噹的漿料組成類型及含量對提高試樣的燒成緻密度、降低高頻介電損耗、改善微觀結構均有明顯的影響;850℃燒結試樣10 MHz測試,相對介電常數為7.7,介電損耗2.0×10-4,25~500℃熱膨脹繫數(7.30~7.65)×10-6/℃,滿足模塊級LTCC大麵積高密度封裝要求。
차조고효류연성형공예,탐토료다충용제조합여분산제대파리/도자장료체계류변성능적영향,통과대파리/도자료、소화제여점결제등배제장료적조성배비진행우화설계,상세연구료장료중각조성함량대류연생료대체적밀도,이급대소성후파리/도자치밀도、물상등미관결구여성능적영향。결과표명,괄당적장료조성류형급함량대제고시양적소성치밀도、강저고빈개전손모、개선미관결구균유명현적영향;850℃소결시양10 MHz측시,상대개전상수위7.7,개전손모2.0×10-4,25~500℃열팽창계수(7.30~7.65)×10-6/℃,만족모괴급LTCC대면적고밀도봉장요구。
The influence of different solvent systems and the dispersant content on the rheological properties of glass/alumina were investigated using efficient tape casting technology.Slurry formulations were optimized by the method of changing the ration of the inorganic to the total present in tape and the ration of plasticizer to binder.The effect of tape-casting slurry composition on bulk density of green tape and bulk density,micro-structure and phase of the sintered samples was studied in detail.The results showed that the appropriate com-position and content of slurries improved bulk density,dielectric properties and microstructure of sintered sam-ples.The samples sintered at 850 ℃ had a dielectric constant of 7.7,a dielectric loss of 2.0×10-4 and a ther-mal expansion coefficient of (7.30-7.65)×10-6/℃ in the range of 25-500 ℃,which satisfied with the require-ments of LTCC packaging materials.