化工学报
化工學報
화공학보
JOURNAL OF CHEMICAL INDUSY AND ENGINEERING (CHINA)
2014年
7期
2620-2628
,共9页
孙容瑾%邱培宇%张春雷%高国%崔大祥
孫容瑾%邱培宇%張春雷%高國%崔大祥
손용근%구배우%장춘뢰%고국%최대상
稀土%发光%量子剪裁%上转换
稀土%髮光%量子剪裁%上轉換
희토%발광%양자전재%상전환
rare earth%luminescence%quantum cutting%up-conversion
稀土元素特殊的电子构型,使其具有优异的光性能,成为新的发光材料的宝库。在照明显示、分析检测等领域,稀土发光材料近年来已经得到了广泛的应用。而且也有多种不同的稀土发光材料问世,如稀土长余辉发光材料和稀土配合物发光材料等。重点介绍了两种新型的稀土发光材料:拥有高效下转换发光效率的稀土掺杂“量子剪裁”发光材料和在生物医学领域有着巨大潜力的稀土掺杂“上转换”发光纳米晶体。对两种发光材料的发光机理进行了描述,并重点展示了两种材料的制备和应用进展。
稀土元素特殊的電子構型,使其具有優異的光性能,成為新的髮光材料的寶庫。在照明顯示、分析檢測等領域,稀土髮光材料近年來已經得到瞭廣汎的應用。而且也有多種不同的稀土髮光材料問世,如稀土長餘輝髮光材料和稀土配閤物髮光材料等。重點介紹瞭兩種新型的稀土髮光材料:擁有高效下轉換髮光效率的稀土摻雜“量子剪裁”髮光材料和在生物醫學領域有著巨大潛力的稀土摻雜“上轉換”髮光納米晶體。對兩種髮光材料的髮光機理進行瞭描述,併重點展示瞭兩種材料的製備和應用進展。
희토원소특수적전자구형,사기구유우이적광성능,성위신적발광재료적보고。재조명현시、분석검측등영역,희토발광재료근년래이경득도료엄범적응용。이차야유다충불동적희토발광재료문세,여희토장여휘발광재료화희토배합물발광재료등。중점개소료량충신형적희토발광재료:옹유고효하전환발광효솔적희토참잡“양자전재”발광재료화재생물의학영역유착거대잠력적희토참잡“상전환”발광납미정체。대량충발광재료적발광궤리진행료묘술,병중점전시료량충재료적제비화응용진전。
Due to their special electronic configurations, rare earth elements have excellent optical properties, which make them a treasure of new luminescent materials. Recently, in the lighting, display, analysis, testing and other areas, rare earth luminescent materials have been widely used. The knowledge gained thus far has allowed the development of various rare earth luminescent materials, such as rare earth long after-glow phosphors and rare earth complexes luminescent materials. Herein two kinds of new rare earth luminescent materials are introduced. They are rare earth doped“quantum cutting” light-emitting materials with efficient down-conversion efficiency and rare earth doped“up-conversion” light-emitting nanocrystals with great potential in the biomedical field. The emitting mechanisms of the two luminescent materials are described, and the progress of preparation and application is highlighted.