浙江化工
浙江化工
절강화공
ZHEJIANG CHEMICAL INDUSTRY
2014年
6期
33-37
,共5页
赵丹%苏露%田香梅%卢久富
趙丹%囌露%田香梅%盧久富
조단%소로%전향매%로구부
硼镓酸盐%离子热反应%晶体结构%表征
硼鎵痠鹽%離子熱反應%晶體結構%錶徵
붕가산염%리자열반응%정체결구%표정
boron gallium%ion thermal reaction%crystal structure%characterization
通过离子热反应合成了一种具有新颖结构的无机-有机杂化镓硼酸盐：Ga(en)2[B5O8(OH)2]·H2O，利用元素分析、FT-IR、XRD及热分析等手段对其进行表征，通过X-射线单晶衍射仪测定其晶体结构。该晶体属于单斜晶系，空间群P2(1)/c，晶胞参数：a=9.2866(3)?， b=12.3169(3)?，c=14.2910(4)?，α=90°，β=96.123(3)°，γ=90°，V=1625.31(8)?3，Z=4。具有由Ga-O-B骨架构筑的一维螺旋链状结构。
通過離子熱反應閤成瞭一種具有新穎結構的無機-有機雜化鎵硼痠鹽：Ga(en)2[B5O8(OH)2]·H2O，利用元素分析、FT-IR、XRD及熱分析等手段對其進行錶徵，通過X-射線單晶衍射儀測定其晶體結構。該晶體屬于單斜晶繫，空間群P2(1)/c，晶胞參數：a=9.2866(3)?， b=12.3169(3)?，c=14.2910(4)?，α=90°，β=96.123(3)°，γ=90°，V=1625.31(8)?3，Z=4。具有由Ga-O-B骨架構築的一維螺鏇鏈狀結構。
통과리자열반응합성료일충구유신영결구적무궤-유궤잡화가붕산염：Ga(en)2[B5O8(OH)2]·H2O，이용원소분석、FT-IR、XRD급열분석등수단대기진행표정，통과X-사선단정연사의측정기정체결구。해정체속우단사정계，공간군P2(1)/c，정포삼수：a=9.2866(3)?， b=12.3169(3)?，c=14.2910(4)?，α=90°，β=96.123(3)°，γ=90°，V=1625.31(8)?3，Z=4。구유유Ga-O-B골가구축적일유라선련상결구。
In this paper, some new crystalline materials with novel structures and useful properties have been constructed by Ga-O-Bmodes. Ga(en)2[B5O8(OH)2]·H2O was synthesized by ion thermal reaction and characterized by elemental analysis , FT-IR, XRD and thermal analysis. The crystal structure of Ga(en)2[B5O8 (OH)2]·H2O was determined by single crystal X-ray diffraction data. The compound Ga(en)2[B5O8(OH)2]·H2O is Monoclinic, space group is P2 (1)/c, with unit cell dimension a = 9.2866 (3) ?, b = 12.3169 (3) ?, c =14.2910(4) ?, α = 90°, β = 96.123(3)°, γ = 90°, V=1625.31(8) ?3 Z=4. The compound Ga(en)2[B5O8(OH)2]· H2O have the one-dimensional helical chain builded by the Ga-O-B skeleton.
