CAJ | 학술논문

介绍利用生产环氧氯丙烷的废料（环氧低沸）在无水三氯化铝催化剂作用下，经氯化得到1，2，3-三氯丙烷，进而经消除反应制备高纯度的2，3-二氯丙烯，优化了反应催化剂。并通过红外光谱、核磁共振谱对产品进行了鉴定。
개소이용생산배양록병완적폐료（배양저비）재무수삼록화려최화제작용하，경록화득도1，2，3-삼록병완，진이경소제반응제비고순도적2，3-이록병희，우화료반응최화제。병통과홍외광보、핵자공진보대산품진행료감정。
1,2,3-Trichloropropane was obtained by chlorination from low boiling of epichlorohydrin in the presence of aluminum chloride catalyst. 2,3-Dichloropropene was prepared by elimination reaction using 1,2,3-trichloropropane as the raw material. The catalyst was optimized. The product was identified by IR, NMR Spectroscopy. The method has the advantages of mild reaction conditions, simple equipment, low pollution, low energy consumption and high yield(84.7%).