中国科技论文
中國科技論文
중국과기논문
Sciencepaper Online
2014年
6期
642-647
,共6页
烧结电除尘灰%硫酸钙%碳酸钠%球形碳酸钙
燒結電除塵灰%硫痠鈣%碳痠鈉%毬形碳痠鈣
소결전제진회%류산개%탄산납%구형탄산개
sintering dust%calcium sulfate%sodium carbonate%spherical crystal CaCO3
对包钢烧结电除尘灰进行了浸出试验,研究结果表明浸出液中有较高含量的钾盐和钙盐。为了提升钾盐产品质量和降低硫酸钙结垢对设备安全操作的影响,在回收钾盐之前,需要对浸出液中的硫酸钙盐进行去除。以碳酸钠溶液为沉淀剂,考察了沉淀剂浓度、反应温度、搅拌强度和平衡时间对浸出液中硫酸钙的去除效果及碳酸钙产品晶型晶貌的影响。结果表明,钙离子去除率几乎达到100%,同时获得了粒径10μm 左右、颗粒分散均匀、高附加值的球形碳酸钙副产品。
對包鋼燒結電除塵灰進行瞭浸齣試驗,研究結果錶明浸齣液中有較高含量的鉀鹽和鈣鹽。為瞭提升鉀鹽產品質量和降低硫痠鈣結垢對設備安全操作的影響,在迴收鉀鹽之前,需要對浸齣液中的硫痠鈣鹽進行去除。以碳痠鈉溶液為沉澱劑,攷察瞭沉澱劑濃度、反應溫度、攪拌彊度和平衡時間對浸齣液中硫痠鈣的去除效果及碳痠鈣產品晶型晶貌的影響。結果錶明,鈣離子去除率幾乎達到100%,同時穫得瞭粒徑10μm 左右、顆粒分散均勻、高附加值的毬形碳痠鈣副產品。
대포강소결전제진회진행료침출시험,연구결과표명침출액중유교고함량적갑염화개염。위료제승갑염산품질량화강저류산개결구대설비안전조작적영향,재회수갑염지전,수요대침출액중적류산개염진행거제。이탄산납용액위침정제,고찰료침정제농도、반응온도、교반강도화평형시간대침출액중류산개적거제효과급탄산개산품정형정모적영향。결과표명,개리자거제솔궤호체도100%,동시획득료립경10μm 좌우、과립분산균균、고부가치적구형탄산개부산품。
Water leaching experiments on the sintering dust collected from Baogang Steel Corporation were carried out.The re-sults show that there are large amounts of potassium salt and calcium sulfate in the leaching solution.It implies that calcium sul-fate should be removed in order to obtain the pure potassium chloride and reduce the risk of operation.Using sodium carbonate solution as a precipitating agent,the influences of the concentration of sodium carbonate solution,reaction temperature,stirring speed and equilibrium time on the removal rate of Ca2+ ,the crystal form and shape of the calcium carbonate precipitate were all studied.The results show that almost 100% of Ca2+ can be removed and spherical CaCO3 crystals with mean particle size of 10μm and good dispersion have been obtained.