CAJ | 학술논문

对太原西山矿区8号煤层的肥、焦、瘦、贫等不同烟煤的镜煤组分进行了酸洗脱灰处理，并同时对这些酸洗后的样品进行了红外分峰处理和微量元素含量的测定，发现随着煤的变质程度加深，某些有机基团与某些微量元素呈正相关关系，并因其正相关系数很高而结合的可能性很大；有的呈负相关关系；也有的和微量元素部分呈正相关变化部分则呈负相关变化。因此，将煤的有机基团分为三类：微量元素亲和性有机基团、微量元素憎厌性有机基团和对微量元素既无亲和性也无憎厌性的中性有机基团。微量元素和煤的有机基团之间相互选择性很强。但无论表现为典型的亲和性还是憎厌性，其亲和、憎厌程度的变化波动趋势，均遵循一个统一的变化规律---元素周期律。典型的中性有机基团，对亲石元素和亲铁亲铜元素所表现的亲和、憎厌倾向也有明显不同，有一定的规律可循。煤中不同类型的有机基团和微量元素的正负相关性，即对微量元素的亲和和憎厌性，对元素周期律的响应型式和响应程度差别也很大。
대태원서산광구8호매층적비、초、수、빈등불동연매적경매조분진행료산세탈회처리，병동시대저사산세후적양품진행료홍외분봉처리화미량원소함량적측정，발현수착매적변질정도가심，모사유궤기단여모사미량원소정정상관관계，병인기정상관계수흔고이결합적가능성흔대；유적정부상관관계；야유적화미량원소부분정정상관변화부분칙정부상관변화。인차，장매적유궤기단분위삼류：미량원소친화성유궤기단、미량원소증염성유궤기단화대미량원소기무친화성야무증염성적중성유궤기단。미량원소화매적유궤기단지간상호선택성흔강。단무론표현위전형적친화성환시증염성，기친화、증염정도적변화파동추세，균준순일개통일적변화규률---원소주기률。전형적중성유궤기단，대친석원소화친철친동원소소표현적친화、증염경향야유명현불동，유일정적규률가순。매중불동류형적유궤기단화미량원소적정부상관성，즉대미량원소적친화화증염성，대원소주기률적향응형식화향응정도차별야흔대。
The acid pickling and demineralization for vitrain samples of fat coal, coking coal, lean coal and meager coal from 8# coal seam of Taiyuan Xishan, China was accomplished. Meanwhile, both the trace elements testing and curve fitting of infrared spectra of the samples were carried out. It shows that correlation between some of organic group and trace elements in vitrain may be positive changes, or negative changes, or they suddenly be positive or negative with the deepening of coal metamorphism. Accordingly, organic structure-groups in coal can be divided into three types: affinity organic groups for trace elements, abhorred organic groups for trace elements and the neutral organic groups which neither affinity nor abhorred for trace elements. It is discovered that the mutual selection is very intense between organic groups and trace elements in vitrain. Whether typical affinity organic groups or typical abhorred one for trace elements, their change of affinity or abhorred are all abide by a common law, namely, the element periodic law. Even if neutral ones, its tendency of affinity or abhorred for lithophile element, chalcophile and siderophile elements are obviously different.