CAJ | 학술논문

制备了β-环糊精与油酸的包合物，以包合物为填料制备了一种酚醛树脂磨具。研究了包合物的填充量和摩擦实验条件对磨具力学及摩擦学性能的影响，分析了包合物在树脂磨具中的存在形式及其在摩擦过程中释放油酸并产生自润滑作用的机理。结果表明，当包合物的填充量小于20％时，磨具的抗拉强度和硬度能够完全满足磨具的实际使用条件，且包合物的填充可有效降低磨具摩擦因数和磨损率。在不同的转速和载荷条件下，填充包合物都能减小磨具的摩擦因数，且转速和载荷越高时作用越明显，但相应地，磨损率也越大。磨具中的包合物在摩擦过程中释放出油酸，油酸与β-环糊精的摩擦产物共同作用于对磨面上形成自润滑层，从而产生减摩、抗磨和提高表面质量的效果。
제비료β-배호정여유산적포합물，이포합물위전료제비료일충분철수지마구。연구료포합물적전충량화마찰실험조건대마구역학급마찰학성능적영향，분석료포합물재수지마구중적존재형식급기재마찰과정중석방유산병산생자윤활작용적궤리。결과표명，당포합물적전충량소우20％시，마구적항랍강도화경도능구완전만족마구적실제사용조건，차포합물적전충가유효강저마구마찰인수화마손솔。재불동적전속화재하조건하，전충포합물도능감소마구적마찰인수，차전속화재하월고시작용월명현，단상응지，마손솔야월대。마구중적포합물재마찰과정중석방출유산，유산여β-배호정적마찰산물공동작용우대마면상형성자윤활층，종이산생감마、항마화제고표면질량적효과。
The inclusion complex ofβ-CD and oleic acid was prepared as a filler of phenolic resin-based abrasive tools.The effects of the contents and testing conditions on mechanical and tribologicalproperties of the abrasive tools were investigated.The state of the complex in the abrasive tools was detected and the self-lubricating mechanism of the abrasive tools was analyzed.The results show that the mechanical properties of abrasives decrease with the filling of complex,while the strength and hardness conditions can still meet the using requirements when the content is less than 20%.The fill-ing of complex reduces both the friction coefficient and wear rate of the abrasive tools.Under different loads and velocities,the friction coefficients of abrasives decrease with the filling of complex,and the effects are much better with the increase of loads and velocities,while the wear rate increases in some extent.The oleic acidin the complex is released in the friction process,and the releasing oleic acid works together with β-CD to form a self-lubricating layer on the steel surface.The lubricating layer has effects of self-lubrication,anti-wear and an improvement of the surface quality.