徐州工程学院学报（自然科学版）
徐州工程學院學報（自然科學版）
서주공정학원학보（자연과학판）
JOURNAL OF XUZHOU INSTITUTE OF TECHNOLOGY(NATURAL SCIENCES EDITION)
2014年
3期
68-74
,共7页
董朝晖%吴晓诚%李寿权%葛红卫%王新华
董朝暉%吳曉誠%李壽權%葛紅衛%王新華
동조휘%오효성%리수권%갈홍위%왕신화
储氢材料%硼氢化锂%铝基氢化物%储氢性能
儲氫材料%硼氫化鋰%鋁基氫化物%儲氫性能
저경재료%붕경화리%려기경화물%저경성능
hydrogen storage materials%LiBH4%Al-based hydrides%hydrogen storage properties
以普通 Al粉、LiAlH4和 Li3 AlH6作为 Al 源，分别与 LiBH4进行球磨复合，通过对LiBH4/Al、LiBH4/LiAlH4和LiBH4/Li3 AlH6复合物吸放氢过程的物相分析、放氢性能分析和吸氢性能分析，系统研究不同Al源对LiBH4储氢性能的影响，发现Li3 AlH6分解提供的活性Al促进LiBH4放氢作用明显，并且其放氢产物的可逆吸氢动力学性能也最好。
以普通 Al粉、LiAlH4和 Li3 AlH6作為 Al 源，分彆與 LiBH4進行毬磨複閤，通過對LiBH4/Al、LiBH4/LiAlH4和LiBH4/Li3 AlH6複閤物吸放氫過程的物相分析、放氫性能分析和吸氫性能分析，繫統研究不同Al源對LiBH4儲氫性能的影響，髮現Li3 AlH6分解提供的活性Al促進LiBH4放氫作用明顯，併且其放氫產物的可逆吸氫動力學性能也最好。
이보통 Al분、LiAlH4화 Li3 AlH6작위 Al 원，분별여 LiBH4진행구마복합，통과대LiBH4/Al、LiBH4/LiAlH4화LiBH4/Li3 AlH6복합물흡방경과정적물상분석、방경성능분석화흡경성능분석，계통연구불동Al원대LiBH4저경성능적영향，발현Li3 AlH6분해제공적활성Al촉진LiBH4방경작용명현，병차기방경산물적가역흡경동역학성능야최호。
In this paper ,LiBH4 was ball-milled respectively with Al powder ,LiAlH4 and Li3 AlH6 as the Al source to form hydrogen storage composites .T he effects of Al source on the hydrogen storage proper-ties of LiBH4 were systematically investigated by phase analysis of hydriding/dehydriding process and hy-drogen desorption/absorption properties measurements of LiBH4/Al ,LiBH4/LiAlH4 and LiBH4/Li3 AlH6 composites .It was found that the active Al formed by decoposition of Li3 AlH6 showed eminent improve-ments on the hydrogen decomposition of LiBH4 ,and its dehydrided product showed the best reversible hy-driding kinetics .
