化工进展
化工進展
화공진전
CHEMICAL INDUSTRY AND ENGINEERING PROGRESS
2014年
10期
2778-2784
,共7页
熊道陵%杨金鑫%张团结%许光辉%陈超%王庚亮%罗序燕
熊道陵%楊金鑫%張糰結%許光輝%陳超%王庚亮%囉序燕
웅도릉%양금흠%장단결%허광휘%진초%왕경량%라서연
废润滑油%再生%超临界流体%分子蒸馏%膜%污染
廢潤滑油%再生%超臨界流體%分子蒸餾%膜%汙染
폐윤활유%재생%초림계류체%분자증류%막%오염
waste lubricants%regeneration%supercritical fluid%molecular distillation%membranes%pollution
近年来石油资源短缺和环保意识增长,废润滑油再生工艺也日益受到各国的关注。本文回顾了国内外废润滑油再生工艺的发展历程,对较典型的传统工艺如蒸馏-白土工艺、蒸馏-硫酸-白土工艺和蒸馏-加氢工艺进行了概述,并分析各类型工艺方法的优缺点。重点探讨了废润滑油再生新工艺如分子蒸馏工艺、溶剂精制工艺和膜处理工艺的优缺点和发展前景。总结国内外学者针对以上新工艺的研究,发现分子蒸馏工艺虽然对废润滑油原料的要求有些苛刻并且设备的前期投入较大,但其具有再生废润滑油效率高、品质好等优点,适合大型工业化;超临界流体与膜耦合技术继承了两种技术的优点,大幅提升了废润滑油再生速度和效果,随着机械强度大、化学稳定性好的无机膜材料和超临界流体萃取工艺的快速发展,该项技术也必将成为废润滑油再生的研究热点。
近年來石油資源短缺和環保意識增長,廢潤滑油再生工藝也日益受到各國的關註。本文迴顧瞭國內外廢潤滑油再生工藝的髮展歷程,對較典型的傳統工藝如蒸餾-白土工藝、蒸餾-硫痠-白土工藝和蒸餾-加氫工藝進行瞭概述,併分析各類型工藝方法的優缺點。重點探討瞭廢潤滑油再生新工藝如分子蒸餾工藝、溶劑精製工藝和膜處理工藝的優缺點和髮展前景。總結國內外學者針對以上新工藝的研究,髮現分子蒸餾工藝雖然對廢潤滑油原料的要求有些苛刻併且設備的前期投入較大,但其具有再生廢潤滑油效率高、品質好等優點,適閤大型工業化;超臨界流體與膜耦閤技術繼承瞭兩種技術的優點,大幅提升瞭廢潤滑油再生速度和效果,隨著機械彊度大、化學穩定性好的無機膜材料和超臨界流體萃取工藝的快速髮展,該項技術也必將成為廢潤滑油再生的研究熱點。
근년래석유자원단결화배보의식증장,폐윤활유재생공예야일익수도각국적관주。본문회고료국내외폐윤활유재생공예적발전역정,대교전형적전통공예여증류-백토공예、증류-류산-백토공예화증류-가경공예진행료개술,병분석각류형공예방법적우결점。중점탐토료폐윤활유재생신공예여분자증류공예、용제정제공예화막처리공예적우결점화발전전경。총결국내외학자침대이상신공예적연구,발현분자증류공예수연대폐윤활유원료적요구유사가각병차설비적전기투입교대,단기구유재생폐윤활유효솔고、품질호등우점,괄합대형공업화;초림계류체여막우합기술계승료량충기술적우점,대폭제승료폐윤활유재생속도화효과,수착궤계강도대、화학은정성호적무궤막재료화초림계류체췌취공예적쾌속발전,해항기술야필장성위폐윤활유재생적연구열점。
Waste lubricants regeneration process has become an increasing concern worldwide because of the shortage of petroleum resources and environmental concerns. This paper reviewed the waste lubricants regeneration processes,such as distillation-clay process,distillation-sulfuric acid-clay process and distillation-hydrogenation process,and analyzed the advantages and disadvantages. This paper mainly discussed the characteristic and prospects of the latest technologies,such as molecular distillation process,solvent refining process and membrane treatment process. Molecular distillation process has strict requirements of waste lubricants and relatively high investment cost,but it has good regeneration efficiency quality;therefore,this process is suitable for large-scale industrialization. Supercritical fluid coupled with membrane inherits the advantages of both technologies,significantly improves the rate and performance of waste lubricants regeneration. With rapid development of supercritical fluid extraction process and inorganic membrane materials,this technology will become the hotspot of research in waste lubricants regeneration.