CAJ | 학술논문

碳酸钙是最丰富的生物矿物材料之一，不同形貌、不同晶型的碳酸钙可适用于印刷、陶瓷、涂料、医学等不同领域。模板法因其可以有效地控制合成碳酸钙的形貌、结构和尺寸，而成为目前制备碳酸钙的重要手段之一。本文结合近几年模板法控制合成碳酸钙的发展，综述了利用小分子、天然生物大分子、凝胶体、微乳液、聚合物等介质作为软模板合成碳酸钙的研究进展，同时简述了硬模板法合成碳酸钙的研究进展，分析比较了各种介质作为模板调控碳酸钙的优缺点，综述了模板法制备碳酸钙未来发展的主要方向及面临的问题。在此基础上，指出深入系统研究模板法调控合成碳酸钙的作用机理，结合电化学等现代技术手段，不断完善调控碳酸钙的晶型和形貌的技术，成为未来研究的重点。
탄산개시최봉부적생물광물재료지일，불동형모、불동정형적탄산개가괄용우인쇄、도자、도료、의학등불동영역。모판법인기가이유효지공제합성탄산개적형모、결구화척촌，이성위목전제비탄산개적중요수단지일。본문결합근궤년모판법공제합성탄산개적발전，종술료이용소분자、천연생물대분자、응효체、미유액、취합물등개질작위연모판합성탄산개적연구진전，동시간술료경모판법합성탄산개적연구진전，분석비교료각충개질작위모판조공탄산개적우결점，종술료모판법제비탄산개미래발전적주요방향급면림적문제。재차기출상，지출심입계통연구모판법조공합성탄산개적작용궤리，결합전화학등현대기술수단，불단완선조공탄산개적정형화형모적기술，성위미래연구적중점。
Calcium carbonate is one of most abundant biological minerals. Calcium carbonate with multi-morphologies and different polymorphs can be used in different fields,including printing, ceramics,paints,and medicine. The template method is preferable to other approaches for synthesis of calcium carbonate,as its morphology and polymorph can be effectively controlled by simply altering the nature of template and preparation conditions. This paper reviews the development in preparation of calcium carbonate by using small molecule,natural macromolecule,gel,microemulsion and polymer as soft templates. The synthesis of calcium carbonate by using hard template is also described. The main development directions and problems in preparing calcium carbonate are analyzed by comparing the advantages and disadvantages of various matrixes. Finally,preparation of calcium carbonate and other biomaterials with the template method is prospected. The mechanism of synthesis of calcium carbonate with the template method,and using electrochemistry and other modern technology to improve the technology of controlling polymorphs and morphologies of calcium carbonate should be focused in the future.