CAJ | 학술논문

介绍了二元碳化物与三元碳化物作为前体制备碳化物衍生碳，概述了碳化物衍生碳的几种常见命名，详细阐述了管式炉中氯气高温刻蚀碳化物、多孔化碳材料的制备工艺过程和原理，总结了碳化物衍生碳孔径结构及应用，并着重介绍了在储氢储甲烷和超级电容器电极材料两方面的应用研究。碳化物衍生碳材料的甲烷吸附存储量可以达到18.5%（质量分数），氢的吸附存储量达到6.2%（质量分数），作为超级电容器电极材料，它的质量比电容是120F/g，且具有非常高的体积比电容（90F/cm3），在MEMS等小型化微电子器件中有重要的应用。最后展望了这种新型碳材料通过调控微观结构与改善性能在更多领域的重要应用。
개소료이원탄화물여삼원탄화물작위전체제비탄화물연생탄，개술료탄화물연생탄적궤충상견명명，상세천술료관식로중록기고온각식탄화물、다공화탄재료적제비공예과정화원리，총결료탄화물연생탄공경결구급응용，병착중개소료재저경저갑완화초급전용기전겁재료량방면적응용연구。탄화물연생탄재료적갑완흡부존저량가이체도18.5%（질량분수），경적흡부존저량체도6.2%（질량분수），작위초급전용기전겁재료，타적질량비전용시120F/g，차구유비상고적체적비전용（90F/cm3），재MEMS등소형화미전자기건중유중요적응용。최후전망료저충신형탄재료통과조공미관결구여개선성능재경다영역적중요응용。
In this paper,binary carbides and ternary carbides were introduced as precursors to make carbide-derived carbons (CDCs). Nomenclature in Chinese of carbide-derived carbons was summarized. Preparation processes and principle of high-temperature Cl2-etching in a tube furnace were elaborated. Structure and properties of CDC were summarized,focusing on the latest researches in the fields of hydrogen/methane storage and supercapacitor electrode materials. The storage capacity of CDC was 18.5% for methane and 6.2% for hydrogen. As supercapacitor electrode material,its mass specific capacity was 120F/g and its volume specific capacity reached a very high value of 90F/cm3,which was potentially useful in microelectronic devices,such as MEMS. Finally,CDC could have better applications in more areas by controlling microstructure and improving performance.