广州化工
廣州化工
엄주화공
GUANGZHOU CHEMICAL INDUSTRY AND TECHNOLOGY
2014年
17期
51-53
,共3页
李永红%雷生虎%姬晓灵%汪岭
李永紅%雷生虎%姬曉靈%汪嶺
리영홍%뢰생호%희효령%왕령
双酚A%碳纳米管%离子液体%线性扫描伏安法
雙酚A%碳納米管%離子液體%線性掃描伏安法
쌍분A%탄납미관%리자액체%선성소묘복안법
bisphenol A%carbon nanotubes%ionic liquids%linear sweep voltammetry
构建了一种基于碳纳米管-离子液体复合电极的双酚A( BPA)传感器。采用循环伏安法和线性扫描伏安法( LSV)研究了双酚A在该修饰电极上的电化学行为,并对实验条件进行了优化。在最佳条件下, BPA 的氧化峰电流与其浓度在0.5~100μM范围内有良好的线性关系(r2=0.9980),检出限为0.1μM(S/N=3)。此方法能应用于湖水和塑料袋中BPA的测定,回收率在96.20%~105.20%之间。
構建瞭一種基于碳納米管-離子液體複閤電極的雙酚A( BPA)傳感器。採用循環伏安法和線性掃描伏安法( LSV)研究瞭雙酚A在該脩飾電極上的電化學行為,併對實驗條件進行瞭優化。在最佳條件下, BPA 的氧化峰電流與其濃度在0.5~100μM範圍內有良好的線性關繫(r2=0.9980),檢齣限為0.1μM(S/N=3)。此方法能應用于湖水和塑料袋中BPA的測定,迴收率在96.20%~105.20%之間。
구건료일충기우탄납미관-리자액체복합전겁적쌍분A( BPA)전감기。채용순배복안법화선성소묘복안법( LSV)연구료쌍분A재해수식전겁상적전화학행위,병대실험조건진행료우화。재최가조건하, BPA 적양화봉전류여기농도재0.5~100μM범위내유량호적선성관계(r2=0.9980),검출한위0.1μM(S/N=3)。차방법능응용우호수화소료대중BPA적측정,회수솔재96.20%~105.20%지간。
The bisphenol A ( BPA ) sensor was fabricated successfully based on carbon nanotubes ionic liquid composite electrode ( MWNTs/CILE ).Electrochemical behaviors of bisphenol A at the modified electrodes were investigated by cyclic voltammetry and linear sweep voltammetry ( LSV ).Experimental conditions that influenced the analytical performance of the MWNTs/CILE were optimized.Under optimal conditions , the electrochemical sensor exhibited a wider linearity range from 0.5 μM to 100 μM BPA with a detection limit of 0.1 μM(S/N=3).This method was successfully applied to determine BPA leached from plastic bag and lake water with good recovery , ranging from 96.20%to 105.20%.