CAJ | 학술논문

以纯柠檬酸为碳源，分别使用十六胺（HAD）和4，7，10-三氧-1，13-十三烷二胺作为碳量子点表面钝化剂，采用一步合成法合成油溶性及水溶性2种碳量子点，以此为染料制备出染料敏化太阳能电池，研究了其光电性能和电化学阻抗谱.该电池采用光阳极-电解质-光阴极（对电极）结构.光阳极采用TiO2纳米颗粒多孔薄膜结构，电解质为常用I-/I3-电解质体系，光阴极为Pt薄膜电极.测试结果表明：在AM 1.5G标准太阳光照下，油溶性碳量子点敏化太阳能电池的短路光电流为0.515 mA/cm2，开路光电压为0.461 V，填充因子为63.17%，转化效率为0.15%；水溶性碳量子点敏化太阳能电池的短路光电流为0.598 mA/cm2，开路光电压为0.549 V，填充因子为65.59%，转化效率为0.22%.数值均优于已报道的文献.
이순저몽산위탄원，분별사용십륙알（HAD）화4，7，10-삼양-1，13-십삼완이알작위탄양자점표면둔화제，채용일보합성법합성유용성급수용성2충탄양자점，이차위염료제비출염료민화태양능전지，연구료기광전성능화전화학조항보.해전지채용광양겁-전해질-광음겁（대전겁）결구.광양겁채용TiO2납미과립다공박막결구，전해질위상용I-/I3-전해질체계，광음겁위Pt박막전겁.측시결과표명：재AM 1.5G표준태양광조하，유용성탄양자점민화태양능전지적단로광전류위0.515 mA/cm2，개로광전압위0.461 V，전충인자위63.17%，전화효솔위0.15%；수용성탄양자점민화태양능전지적단로광전류위0.598 mA/cm2，개로광전압위0.549 V，전충인자위65.59%，전화효솔위0.22%.수치균우우이보도적문헌.
With pure citric acid as carbon source, HAD and 4, 7, 10-trioxa-1, 13-tridecanediamine as surface passiviation for carbon quantum dots, carbon quantum dots were synthesized by a one-step reaction in oil phase or aqueous phase and used as sensitizers for the fabrication dye-sensitized solar cells. TiO 2 nanoparticle porous electrode was used as photo-anode and Pt film electrode was used as photo-cathode. The electrolyte was I-/I3-. The photovoltaic performance of the prepared cell were revealt that under AM 1.5G illumination, the Isc, Voc, FF and power conversion efficiency values of oil-soluble carbon quantum dots are 0.515 mA/cm2, 0.461 V, 63.17% and 0.15%, respectively. While, the Isc, Voc and FF values of water-soluble carbon quantum dots are 0.598 mA/cm2, 0.549 V and 65.59%, respectively. Its power conversion efficiency is 0.22%, which are better than the reported results in other papers.