CAJ | 학술논문

研究了氨氯地平(Amlodipine besylate, Aml)在离子液体(1-Benzyl-3-Methylimidazole,[BnMIM]PF6)修饰碳糊电极([BnMIM]PF6/CPE)上的电化学行为和电化学动力学性质，并用循环伏安法(CV)及计时电流法(CA)测得Aml在[BnMIM]PF6/CPE上的电极反应动力学参数。实验结果表明，Aml在[BnMIM]PF6/CPE上发生了受吸附控制的不可逆电化学氧化过程。用方波伏安法(SWV)考察了Aml氧化峰电流与其浓度在1.2×10-6～1.0×10-3 mol/L范围内呈良好的线性关系，检出限(3S/N)3.3×10-7 mol/L，RSD1.3%～3.4%之间，加样回收率98.2%～103%。
연구료안록지평(Amlodipine besylate, Aml)재리자액체(1-Benzyl-3-Methylimidazole,[BnMIM]PF6)수식탄호전겁([BnMIM]PF6/CPE)상적전화학행위화전화학동역학성질，병용순배복안법(CV)급계시전류법(CA)측득Aml재[BnMIM]PF6/CPE상적전겁반응동역학삼수。실험결과표명，Aml재[BnMIM]PF6/CPE상발생료수흡부공제적불가역전화학양화과정。용방파복안법(SWV)고찰료Aml양화봉전류여기농도재1.2×10-6～1.0×10-3 mol/L범위내정량호적선성관계，검출한(3S/N)3.3×10-7 mol/L，RSD1.3%～3.4%지간，가양회수솔98.2%～103%。
The electrochemical behaviors and electrochemical kinetic of Amlodipine besylate at 1-Benzyl-3-Methylimidazole modified carbon paste electrode ([BnMIM]PF6/CPE) were investigated. The electrode reaction kinetic parameters were also determined by cyclic voltammetry(CV) and chronoamperometry(CA) at [BnMIM]PF6/CPE. The experimental results indicated that Aml electrochemical reaction at [BnMIM]PF6/CPE is an irreversible electrochemical oxidation with an adsorption -controlled process. The oxidation peak currents versus Aml concentration have a good linear relationship in the concentration range of 1.2 ×10 -6~1.0 ×10 -3 mol/L with the correlation coefficient of 0.996 5, the detection limit (3S/N) of 3.3 × 10-7 mol/L, the relative standard deviation (RSD) as between 1.3%~3.4%and the standard addition recoverage as in the range of 98.2%~103%by SWV.