CAJ | 학술논문

CdSO4·8/3H2O与5-氨基四唑-1-乙酸（Hatza）（Hatza=5-aminotetrazole-1-acetic acid）及4，4′-联吡啶（4，4’-bipy）在水和乙醇的混合溶液中反应，生成了一个新的配合物[Cd（atza）2（4，4'-bipy）0.5（H2O）].通过元素分析，红外光谱和X-射线单晶衍射对此配合物进行了表征.该配合物晶体结构属单斜晶系，主要晶体结构数据：空间群P21/c，a=10.356（2），b=13.482（3），c=13.230（3）?，β=111.18（3）（°）.在此晶体中，Cd（II）与两个来自atza配体的两个氧原子、两个来自atza配体的两个氮原子、一个水分子的一个氧原子及一个4，4’-bipy配体的一个氮原子配位，配位数为6，配位构型为变形的八面体.每个atza作为双齿配体与两个Cd（II）配位，通过atza和4，4’-联吡啶配体的桥联作用，该配合物形成了沿bc面伸展的二维结构.相邻的面之间通过氢键作用，形成了三维结构.此外，在室温下研究了配合物固体荧光特性.
CdSO4·8/3H2O여5-안기사서-1-을산（Hatza）（Hatza=5-aminotetrazole-1-acetic acid）급4，4′-련필정（4，4’-bipy）재수화을순적혼합용액중반응，생성료일개신적배합물[Cd（atza）2（4，4'-bipy）0.5（H2O）].통과원소분석，홍외광보화X-사선단정연사대차배합물진행료표정.해배합물정체결구속단사정계，주요정체결구수거：공간군P21/c，a=10.356（2），b=13.482（3），c=13.230（3）?，β=111.18（3）（°）.재차정체중，Cd（II）여량개래자atza배체적량개양원자、량개래자atza배체적량개담원자、일개수분자적일개양원자급일개4，4’-bipy배체적일개담원자배위，배위수위6，배위구형위변형적팔면체.매개atza작위쌍치배체여량개Cd（II）배위，통과atza화4，4’-련필정배체적교련작용，해배합물형성료연bc면신전적이유결구.상린적면지간통과경건작용，형성료삼유결구.차외，재실온하연구료배합물고체형광특성.
A reaction of CdSO4 with Hatza (Hatza=5-aminotetrazole-1-acetic acid) and 4,4’-bipy, produced a new coordination compound [Cd(atza)2(4,4’-bipy)0.5(H2O)]. This compound was structurally characterized by ele-mental analysis, IR and single-crystal X-ray diffraction. It crystallizes in monoclinic space group P21/c. Crystal parameters: a=10.356(2), b=13.482(3), c=13.230(3)?, β=111.18(3) (°). Each Cd center is six-coordinated by two oxygen atoms from two atza ligands, one oxygen atom from one water molecule and two nitrogen atoms from atza ligand and 4,4’-bipy ligand, respectively, forming a distorted octahedral coordination geometry. This compound displays a 2D layer network via the bridging mode of atza and 4,4’-bipy ligands and further generates a 3D net-work through hydrogen bonding interactions. Furthermore, the luminescence properties were also investigated at room temperature in the solid state.