热力发电
熱力髮電
열력발전
THERMAL POWER GENERATION
2014年
5期
1-6,12
,共7页
离子液%二氧化碳捕集%物理吸收%化学吸收
離子液%二氧化碳捕集%物理吸收%化學吸收
리자액%이양화탄포집%물리흡수%화학흡수
ionic liquids%carbon dioxide capture%physical absorption%chemical absorption%mecha-nism
离子液完全是由特定的阴、阳离子所构成的有机盐,在室温或近于室温下呈液态,通过调整阴阳离子结构或加入功能化基团,可形成具有特定功能、任务专一的吸收剂,其用于CO2固定显示出良好性能。普通离子液主要利用离子间特有的自由空间固定CO2,这种物理吸收过程需要较高的压力,且吸收容量较低;功能化离子液中通过引入碱性功能基团来吸收CO2,提高了离子液对CO2的吸收容量。
離子液完全是由特定的陰、暘離子所構成的有機鹽,在室溫或近于室溫下呈液態,通過調整陰暘離子結構或加入功能化基糰,可形成具有特定功能、任務專一的吸收劑,其用于CO2固定顯示齣良好性能。普通離子液主要利用離子間特有的自由空間固定CO2,這種物理吸收過程需要較高的壓力,且吸收容量較低;功能化離子液中通過引入堿性功能基糰來吸收CO2,提高瞭離子液對CO2的吸收容量。
리자액완전시유특정적음、양리자소구성적유궤염,재실온혹근우실온하정액태,통과조정음양리자결구혹가입공능화기단,가형성구유특정공능、임무전일적흡수제,기용우CO2고정현시출량호성능。보통리자액주요이용리자간특유적자유공간고정CO2,저충물리흡수과정수요교고적압력,차흡수용량교저;공능화리자액중통과인입감성공능기단래흡수CO2,제고료리자액대CO2적흡수용량。
Ionic liquids (IL)are completely the liquid compounds composed of specific cation and anion existing at or close to room temperature in the liquid state.Ionic liquids have been consid-ered as a kind of potential candidates for CO2 capture,on the basis of their unique properties like easy structural modification or functionalization,especially their strong affinity to CO2 .In the con-ventional ILs,CO2 is absorbed by occupying the free space between the ions,high pressure is nee-ded in this physical absorption process,and the absorption capacity is relatively low.Functional-ized ILs is another good option for CO2 absorption,which is a chemical process.Taking into ac-count the chemical interaction of amino with CO2 molecule,introduction of amino-group or other alkaline groups into IL would construct functionalized ionic liquids for the CO2 removal.In this paper,the mechanism and research progress of the absorption of CO2 by ionic liquid are intro-duced.Furthermore,the prospect for the development and direction of the ionic liquid CO2 fixation is indicated.