海洋科学
海洋科學
해양과학
MARINE SCIENCES
2014年
5期
16-23
,共8页
刘进%刘峥%谢思维%刘宝玉
劉進%劉崢%謝思維%劉寶玉
류진%류쟁%사사유%류보옥
复配型缓蚀剂%海水%碳钢%缓蚀性能
複配型緩蝕劑%海水%碳鋼%緩蝕性能
복배형완식제%해수%탄강%완식성능
compounding Schiff base corrosion inhibitor%ocean%carbon steel%corrosion performance
设计了由邻氧乙酸苯甲醛-4-吡啶甲酰腙席夫碱80 mg/L,邻香草醛脱氢枞胺席夫碱6 mg/L, ZnSO450 mg/L, Tween-80100 mg/L四元复配缓蚀剂,通过失重法、极化曲线法和电化学交流阻抗技术,研究了该复配缓蚀剂在模拟现实使用环境中的缓蚀性能。结果表明,该复配缓蚀剂的缓蚀率受海水盐度的影响不大,但该复配缓蚀剂的缓蚀性能受海水温度和海水流速的影响较大,当温度低于50℃和流速较低、缓蚀剂浓度为临界浓度时,缓蚀剂对碳钢有很好的抑制作用,而有锈试样和间浸实验发现高浓度的复配缓蚀剂可以抑制碳钢的腐蚀。
設計瞭由鄰氧乙痠苯甲醛-4-吡啶甲酰腙席伕堿80 mg/L,鄰香草醛脫氫樅胺席伕堿6 mg/L, ZnSO450 mg/L, Tween-80100 mg/L四元複配緩蝕劑,通過失重法、極化麯線法和電化學交流阻抗技術,研究瞭該複配緩蝕劑在模擬現實使用環境中的緩蝕性能。結果錶明,該複配緩蝕劑的緩蝕率受海水鹽度的影響不大,但該複配緩蝕劑的緩蝕性能受海水溫度和海水流速的影響較大,噹溫度低于50℃和流速較低、緩蝕劑濃度為臨界濃度時,緩蝕劑對碳鋼有很好的抑製作用,而有鏽試樣和間浸實驗髮現高濃度的複配緩蝕劑可以抑製碳鋼的腐蝕。
설계료유린양을산분갑철-4-필정갑선종석부감80 mg/L,린향초철탈경종알석부감6 mg/L, ZnSO450 mg/L, Tween-80100 mg/L사원복배완식제,통과실중법、겁화곡선법화전화학교류조항기술,연구료해복배완식제재모의현실사용배경중적완식성능。결과표명,해복배완식제적완식솔수해수염도적영향불대,단해복배완식제적완식성능수해수온도화해수류속적영향교대,당온도저우50℃화류속교저、완식제농도위림계농도시,완식제대탄강유흔호적억제작용,이유수시양화간침실험발현고농도적복배완식제가이억제탄강적부식。
The quaternary compound corrosion inhibitor containing neighbouring oxygen ethanoic acid benzene formaldehyde-4-pyridine formyl hydrazone schiff base (80 mg/L), adjacent dehydroabietic vanilla aldehyde amine schiff base (6 mg/L), ZnSO4 (50 mg/L, ) and Tween-80, (100 mg/L) , were studied using weight loss method, polarization curves, AC impedance in a series of simulated actual used environments, The results showed that the inhibitive efficiency of the compound corrosion inhibitor was only slightly affected by salinity, but significantly affected by ocean temperature and flow rate. The corrosion inhibitor had good inhibition effect on carbon steel when the temperature was lower than 50℃, the flow rate was low and the corrosion inhibitor concentration was at a critical concentration. The high concentrations of compound corrosion inhibitor could inhibit the corrosion of carbon steel in rust sample and leaching experiments.