化学与生物工程
化學與生物工程
화학여생물공정
CHEMISTRY & BIOENGINEERING
2014年
7期
61-63
,共3页
任铜彦%韩园园%张萌萌%何平%张便利
任銅彥%韓園園%張萌萌%何平%張便利
임동언%한완완%장맹맹%하평%장편리
超级电容器%α-MnO2 纳米针电极%比电容%循环寿命
超級電容器%α-MnO2 納米針電極%比電容%循環壽命
초급전용기%α-MnO2 납미침전겁%비전용%순배수명
supercapacitor%α-MnO2 nanoneedles electrode%specific storage%cy cle life
通过简单的水热法合成了α-MnO2纳米针,将其用作超级电容器电极材料,通过循环伏安和恒电流充放电测试手段对α-MnO2纳米针电极进行分析。结果表明,以1 mol· L-1 Na2 SO4为电解液,电极在-0.6~0.6 V的电压范围内具有良好的法拉第电容特性;在电流密度为0.01 A·g-1时,电极的比电容最高达56.7 F·g-1,且500次循环后,比电容保持率为82%,表明其具有良好的循环性能。
通過簡單的水熱法閤成瞭α-MnO2納米針,將其用作超級電容器電極材料,通過循環伏安和恆電流充放電測試手段對α-MnO2納米針電極進行分析。結果錶明,以1 mol· L-1 Na2 SO4為電解液,電極在-0.6~0.6 V的電壓範圍內具有良好的法拉第電容特性;在電流密度為0.01 A·g-1時,電極的比電容最高達56.7 F·g-1,且500次循環後,比電容保持率為82%,錶明其具有良好的循環性能。
통과간단적수열법합성료α-MnO2납미침,장기용작초급전용기전겁재료,통과순배복안화항전류충방전측시수단대α-MnO2납미침전겁진행분석。결과표명,이1 mol· L-1 Na2 SO4위전해액,전겁재-0.6~0.6 V적전압범위내구유량호적법랍제전용특성;재전류밀도위0.01 A·g-1시,전겁적비전용최고체56.7 F·g-1,차500차순배후,비전용보지솔위82%,표명기구유량호적순배성능。
α-MnO2 Nanoneedles were synthesized by simple hydrothermal method and had been used as the supercapacitor electrode materials.Theα-MnO2 nanoneedles electrodes had been characterized by cyclic voltam-metry and galvanostatic charge-discharge tests.The results indicated that the electrodes had good Faraday ca-pacitive performance in the range of -0.6~0.6 V by using 1 mol·L-1 Na2 SO4 solution as electrolyte.Under current density of 0.01 A·g-1 ,the specific storage could up to the highest of 56.7 F·g-1 ,and remained 82%after 500 cycles,which showed the electrode possessed good cyclic stability.