化工进展
化工進展
화공진전
CHEMICAL INDUSTRY AND ENGINEERING PROGRESS
2014年
8期
1941-1950
,共10页
李春喜%熊佳丽%孟洪%陆颖舟
李春喜%熊佳麗%孟洪%陸穎舟
리춘희%웅가려%맹홍%륙영주
离子液体%聚合物%聚合离子液体%介孔材料
離子液體%聚閤物%聚閤離子液體%介孔材料
리자액체%취합물%취합리자액체%개공재료
ionic liquid%polymer%poly ionic liquid%mesoporous materials
聚合离子液体(PILs)是一种特殊聚电解质,兼具聚合物和离子液体(ILs)特性。根据PILs组成和结构的变化,它可以是固体、液体或凝胶状软物质,目前已成为ILs和介孔聚合材料领域的前沿研究方向之一。本文简要回顾了ILs的特性、潜在应用及其设计和应用过程中面临的挑战,分析了PILs概念提出的必然性,综述了PILs的主要合成方法、ILs单体的种类以及PILs性质和多尺度结构的调控方法,指出未来PILs的研究方向应集中在如下几个方面:PILs的新合成路线、产品的系统表征(如相对分子质量、链段结构、微/介观结构、机械强度和机械加工性等)以及PILs的组成-结构-性质关系,为面向特定应用的PILs材料的设计提供理论指导。
聚閤離子液體(PILs)是一種特殊聚電解質,兼具聚閤物和離子液體(ILs)特性。根據PILs組成和結構的變化,它可以是固體、液體或凝膠狀軟物質,目前已成為ILs和介孔聚閤材料領域的前沿研究方嚮之一。本文簡要迴顧瞭ILs的特性、潛在應用及其設計和應用過程中麵臨的挑戰,分析瞭PILs概唸提齣的必然性,綜述瞭PILs的主要閤成方法、ILs單體的種類以及PILs性質和多呎度結構的調控方法,指齣未來PILs的研究方嚮應集中在如下幾箇方麵:PILs的新閤成路線、產品的繫統錶徵(如相對分子質量、鏈段結構、微/介觀結構、機械彊度和機械加工性等)以及PILs的組成-結構-性質關繫,為麵嚮特定應用的PILs材料的設計提供理論指導。
취합리자액체(PILs)시일충특수취전해질,겸구취합물화리자액체(ILs)특성。근거PILs조성화결구적변화,타가이시고체、액체혹응효상연물질,목전이성위ILs화개공취합재료영역적전연연구방향지일。본문간요회고료ILs적특성、잠재응용급기설계화응용과정중면림적도전,분석료PILs개념제출적필연성,종술료PILs적주요합성방법、ILs단체적충류이급PILs성질화다척도결구적조공방법,지출미래PILs적연구방향응집중재여하궤개방면:PILs적신합성로선、산품적계통표정(여상대분자질량、련단결구、미/개관결구、궤계강도화궤계가공성등)이급PILs적조성-결구-성질관계,위면향특정응용적PILs재료적설계제공이론지도。
Poly ionic liquids (PILs) are a new kind of polyelectrolytes with structural and properties characteristics of both polymers and ionic liquids (ILs),which may overcome some of the intrinsic demerits of ILs. PILs may be solid,liquid or gel like soft matter with varying micro/meso structures and functionalities,and have become one of the research frontiers in both ILs and mesoporous polymer materials. This paper reviews the characteristics of ILs and the bottlenecks confronting their potential use,explains the necessity of development of PILs,and summarizes main kinds of the ILs monomers, synthesis approaches of PILs and methods for tuning their micro/meso structures and properties. Finally future research topics are stressed , including novel synthesis approaches , systematic characterization of PILs,as well as determination of the constitution-structure-properties relationship thereof toward molecular design for the task-specific PILs materials.