光谱学与光谱分析
光譜學與光譜分析
광보학여광보분석
SPECTROSCOPY AND SPECTRAL ANALYSIS
2014年
8期
2273-2278
,共6页
张志丹%李桥%罗香丽%姜海超%郑庆福%赵兰坡%王继红
張誌丹%李橋%囉香麗%薑海超%鄭慶福%趙蘭坡%王繼紅
장지단%리교%라향려%강해초%정경복%조란파%왕계홍
XRD光谱%利用方式%盐碱土%粘粒矿物%演化
XRD光譜%利用方式%鹽堿土%粘粒礦物%縯化
XRD광보%이용방식%염감토%점립광물%연화
XRD spectrum%Use pattern%Saline-alkali soil%Clay minerals%Evolution
以吉林省典型盐碱土为研究对象,对比分析水田与旱田利用方式下土壤粘粒矿物的组成特征,并利用X射线衍射(XRD)光谱研究两种利用方式下粘粒矿物的演化规律。结果表明,水田利用方式下,盐碱土各项理化性质均优于旱田利用,且水田利用较旱田利用更能促进盐碱土颗粒风化,提高粉粒颗粒含量。水田利用下土壤有强烈的脱钾过程,粘粒矿物的水化程度较高,伊利石结晶度降低。XRD光谱分析表明,两种利用方式下粘粒矿物组成相似,但衍射峰的强度及峰位存在差异。旱田利用的盐碱土粘粒矿物演变过程主要为S/I混层矿物→蛭石,水田方式下演变过程则主要为黑云母→伊利石和S/I混层矿物→蛭石→高岭石;长期水田利用后的盐碱土会出现一类羟基化的“绿泥石化”矿物。研究结果表明水田利用更有助于改善土壤结构,培育高肥力土壤,对盐碱土的改良效果较好。利用XRD光谱分析方法,较为全面的测定了粘粒矿物的各项特性,并针对两种利用方式进行对比分析,是土壤矿物研究的新视角。
以吉林省典型鹽堿土為研究對象,對比分析水田與旱田利用方式下土壤粘粒礦物的組成特徵,併利用X射線衍射(XRD)光譜研究兩種利用方式下粘粒礦物的縯化規律。結果錶明,水田利用方式下,鹽堿土各項理化性質均優于旱田利用,且水田利用較旱田利用更能促進鹽堿土顆粒風化,提高粉粒顆粒含量。水田利用下土壤有彊烈的脫鉀過程,粘粒礦物的水化程度較高,伊利石結晶度降低。XRD光譜分析錶明,兩種利用方式下粘粒礦物組成相似,但衍射峰的彊度及峰位存在差異。旱田利用的鹽堿土粘粒礦物縯變過程主要為S/I混層礦物→蛭石,水田方式下縯變過程則主要為黑雲母→伊利石和S/I混層礦物→蛭石→高嶺石;長期水田利用後的鹽堿土會齣現一類羥基化的“綠泥石化”礦物。研究結果錶明水田利用更有助于改善土壤結構,培育高肥力土壤,對鹽堿土的改良效果較好。利用XRD光譜分析方法,較為全麵的測定瞭粘粒礦物的各項特性,併針對兩種利用方式進行對比分析,是土壤礦物研究的新視角。
이길림성전형염감토위연구대상,대비분석수전여한전이용방식하토양점립광물적조성특정,병이용X사선연사(XRD)광보연구량충이용방식하점립광물적연화규률。결과표명,수전이용방식하,염감토각항이화성질균우우한전이용,차수전이용교한전이용경능촉진염감토과립풍화,제고분립과립함량。수전이용하토양유강렬적탈갑과정,점립광물적수화정도교고,이리석결정도강저。XRD광보분석표명,량충이용방식하점립광물조성상사,단연사봉적강도급봉위존재차이。한전이용적염감토점립광물연변과정주요위S/I혼층광물→질석,수전방식하연변과정칙주요위흑운모→이리석화S/I혼층광물→질석→고령석;장기수전이용후적염감토회출현일류간기화적“록니석화”광물。연구결과표명수전이용경유조우개선토양결구,배육고비력토양,대염감토적개량효과교호。이용XRD광보분석방법,교위전면적측정료점립광물적각항특성,병침대량충이용방식진행대비분석,시토양광물연구적신시각。
The present paper took the typical saline-alkali soil in Jilin province as study object,and determinated the soil clay mineral composition characteristics of soil in paddy field and dry land.Then XRD spectrum was used to analyze the evolutionary mechanism of clay mineral in the two kinds of soil.The results showed that the physical and chemical properties of soil in paddy field were better than those in dry land,and paddy field would promote the weathering of mineral particles in saline-alkali soil and enhance the silt content.Paddy field soil showed a strong potassium-removal process,with a higher degree of clay mineral hydration and lower degree of illite crystallinity.Analysis of XRD spectrum showed that the clay mineral composition was similar in two kinds of soil,while the intensity and position of diffraction peak showed difference.The evolution process of clay mineral in dry land was S/I mixture→vermiculite,while in paddy field it was S/I mixture→vermiculite→kaolinite.One kind of hydroxyl-ated'chlorite'mineral would appear in saline-alkali soil in long-term cultivated paddy field.Taking into account that the physical and chemical properties of soil in paddy field were better then those in dry land,we could know that paddy field could help much improve soil structure,cultivate high-fertility soil and improve saline-alkali soil.This paper used XRD spectrum to determine the characteristics of clay minerals comprehensively,and analyzed two kinds of land use comparatively,and was a new perspective of soil minerals study.