化工进展
化工進展
화공진전
CHEMICAL INDUSTRY AND ENGINEERING PROGRESS
2014年
8期
2174-2179
,共6页
镉%污染%土壤%修复%生物钝化%微生物
鎘%汙染%土壤%脩複%生物鈍化%微生物
력%오염%토양%수복%생물둔화%미생물
Cadmium%pollution%soil%remediation%biostabilization%microorganism
回顾了我国含镉土壤的场地修复。综述了利用生物钝化技术修复镉污染土壤的研究现状,重点探讨了微生物的代谢产物与镉产生硫化物或磷酸盐沉淀的微生物沉淀作用、微生物的细胞壁和其分泌的胞外聚合物直接吸附镉的微生物吸附作用以及镉离子透过微生物的细胞膜而被固定在细胞内的微生物摄取作用等生物钝化机理,并对有机钝化过程和无机钝化过程进行了介绍和评价。分析了镉在土壤中的离子交换态、碳酸盐结合态、铁锰氧化物结合态、有机结合态和残渣态等赋存形态以及土壤中pH值、氧化还原电位、有机质、共存重金属和微生物等因素对镉的生物可利用度的影响。最后阐述了生物钝化技术的优点以及该技术不能将重金属从土壤中永久去除的问题,指出生物钝化技术与其他修复方法相结合是其未来的发展方向。
迴顧瞭我國含鎘土壤的場地脩複。綜述瞭利用生物鈍化技術脩複鎘汙染土壤的研究現狀,重點探討瞭微生物的代謝產物與鎘產生硫化物或燐痠鹽沉澱的微生物沉澱作用、微生物的細胞壁和其分泌的胞外聚閤物直接吸附鎘的微生物吸附作用以及鎘離子透過微生物的細胞膜而被固定在細胞內的微生物攝取作用等生物鈍化機理,併對有機鈍化過程和無機鈍化過程進行瞭介紹和評價。分析瞭鎘在土壤中的離子交換態、碳痠鹽結閤態、鐵錳氧化物結閤態、有機結閤態和殘渣態等賦存形態以及土壤中pH值、氧化還原電位、有機質、共存重金屬和微生物等因素對鎘的生物可利用度的影響。最後闡述瞭生物鈍化技術的優點以及該技術不能將重金屬從土壤中永久去除的問題,指齣生物鈍化技術與其他脩複方法相結閤是其未來的髮展方嚮。
회고료아국함력토양적장지수복。종술료이용생물둔화기술수복력오염토양적연구현상,중점탐토료미생물적대사산물여력산생류화물혹린산염침정적미생물침정작용、미생물적세포벽화기분비적포외취합물직접흡부력적미생물흡부작용이급력리자투과미생물적세포막이피고정재세포내적미생물섭취작용등생물둔화궤리,병대유궤둔화과정화무궤둔화과정진행료개소화평개。분석료력재토양중적리자교환태、탄산염결합태、철맹양화물결합태、유궤결합태화잔사태등부존형태이급토양중pH치、양화환원전위、유궤질、공존중금속화미생물등인소대력적생물가이용도적영향。최후천술료생물둔화기술적우점이급해기술불능장중금속종토양중영구거제적문제,지출생물둔화기술여기타수복방법상결합시기미래적발전방향。
The site remediation of Cadmium contaminated soil was reviewed.The recent research in biostabilization of Cadmium in contaminated soil was summarized.The stabilization mechanisms were discussed with highlight,such as the bioprecipitation that microbial metabolites can react with Cadmium to form sulfide or phosphate precipitation,the biosorption that microbial cell walls and extracellular polymeric substances can adsorb Cadmium,and the biological uptake that Cadmium ions can pass through the cell membrane of microorganisms and be fixed in cells.Organic and inorganic stabilization were also introduced and evaluated.The state,e.g. ion-exchangeable,bound to carbonates, bound to iron and manganese oxides,bound to organic matter,and residual of Cadmium in soil,and the factors of pH,redox potential,organic matters,coexistent heavy metals and microorganisms which affect the consequential bioavailability of Cadmium were analyzed. Finally , the advantages of biostabilization technique and the fact that heavy metals cannot be removed from soil permanently by this technique were clarified,and the future direction that biostabilization technique should be combined with other techniques was pointed out.