吉林大学学报(理学版)
吉林大學學報(理學版)
길림대학학보(이학판)
JOURNAL OF JILIN UNIVERSITY(SCIENCE EDITION)
2014年
4期
802-806
,共5页
锂离子电池%负极材料%多孔碳%生物质%咖啡渣
鋰離子電池%負極材料%多孔碳%生物質%咖啡渣
리리자전지%부겁재료%다공탄%생물질%가배사
lithium ion battery%anode material%porous carbon%biomass%coffee grounds
以咖啡渣为原料,利用碳化与活化反应制备出多孔的碳材料,并利用 X 射线衍射、扫描电子显微镜、Raman 光谱和 N2吸附脱附等方法分析该材料的物理化学性质.结果表明:该材料具有较高的石墨化程度;当质量电流密度为0.1 A/g 时,其首圈放电和充电质量比容量值分别为1029 mA·h/g 和461 mA·h/g,且循环稳定性较好,其质量比容量远高于石墨的理论容量(372 mA·h/g).
以咖啡渣為原料,利用碳化與活化反應製備齣多孔的碳材料,併利用 X 射線衍射、掃描電子顯微鏡、Raman 光譜和 N2吸附脫附等方法分析該材料的物理化學性質.結果錶明:該材料具有較高的石墨化程度;噹質量電流密度為0.1 A/g 時,其首圈放電和充電質量比容量值分彆為1029 mA·h/g 和461 mA·h/g,且循環穩定性較好,其質量比容量遠高于石墨的理論容量(372 mA·h/g).
이가배사위원료,이용탄화여활화반응제비출다공적탄재료,병이용 X 사선연사、소묘전자현미경、Raman 광보화 N2흡부탈부등방법분석해재료적물이화학성질.결과표명:해재료구유교고적석묵화정도;당질량전류밀도위0.1 A/g 시,기수권방전화충전질량비용량치분별위1029 mA·h/g 화461 mA·h/g,차순배은정성교호,기질량비용량원고우석묵적이론용량(372 mA·h/g).
An easy carbonization and activation approach was employed to synthesize porous carbon material with coffee grounds as carbon source.X-ray diffraction (XRD),Raman spectroscopy,and scanning electron microscopy (SEM)show that the prepared material possesses a disordered structure with a relatively high graphitization degree.The existence of mesopores was confirmed by the nitrogen adsorption/desorption isotherms as well as the pore size distribution curve.At a mass current density of 0.1 A/g,the initial discharge and charge capacities of the prepared material can reach as high as 1 029 and 461 mA·h/g,respectively,much higher than the theoretical capacity of graphite (372 mA·h/g).