分析仪器
分析儀器
분석의기
ANALYTICAL INSTRUMENTATION
2014年
4期
33-36
,共4页
易勇%刘克清%张浩%刘卫丽%王文利%陈凡斌
易勇%劉剋清%張浩%劉衛麗%王文利%陳凡斌
역용%류극청%장호%류위려%왕문리%진범빈
磷酸三丁酯%固井水泥浆添加剂%气相色谱-质谱法
燐痠三丁酯%固井水泥漿添加劑%氣相色譜-質譜法
린산삼정지%고정수니장첨가제%기상색보-질보법
tributyl phosphate%cementing slurry additives%GC-M S
采用气相色谱-质谱法测定固井水泥浆添加剂中磷酸三丁酯（TBP）的含量。选择m/z＝99、155和211的麦氏重排离子为特征离子。TBP在0.20 g/L～5.13g/L含量范围内，其特征离子丰度与含量呈线性关系，线性方程为：Y＝1.05×107 X＋1.75×105，相关系数γ2＝0.999，方法检出限（S/N＝3）0.000073g/L ，定量限（S/N＝10）0.00024g/L ，平均回收率为106.2％～109.2，相对标准偏差为0.36％～1.70％（n＝6）。实际应用表明：该方法适用于油田固井水泥浆添加剂中磷酸三丁酯的质控分析。
採用氣相色譜-質譜法測定固井水泥漿添加劑中燐痠三丁酯（TBP）的含量。選擇m/z＝99、155和211的麥氏重排離子為特徵離子。TBP在0.20 g/L～5.13g/L含量範圍內，其特徵離子豐度與含量呈線性關繫，線性方程為：Y＝1.05×107 X＋1.75×105，相關繫數γ2＝0.999，方法檢齣限（S/N＝3）0.000073g/L ，定量限（S/N＝10）0.00024g/L ，平均迴收率為106.2％～109.2，相對標準偏差為0.36％～1.70％（n＝6）。實際應用錶明：該方法適用于油田固井水泥漿添加劑中燐痠三丁酯的質控分析。
채용기상색보-질보법측정고정수니장첨가제중린산삼정지（TBP）적함량。선택m/z＝99、155화211적맥씨중배리자위특정리자。TBP재0.20 g/L～5.13g/L함량범위내，기특정리자봉도여함량정선성관계，선성방정위：Y＝1.05×107 X＋1.75×105，상관계수γ2＝0.999，방법검출한（S/N＝3）0.000073g/L ，정량한（S/N＝10）0.00024g/L ，평균회수솔위106.2％～109.2，상대표준편차위0.36％～1.70％（n＝6）。실제응용표명：해방법괄용우유전고정수니장첨가제중린산삼정지적질공분석。
A method was established for the determination of tributyl phosphate (TBP) in cementing slurry additives by GC-MS. The characteristic ions were chosen at the m/z of 99 ,155 ,and 211 by McLaf-ferty rearrangement. The TBP content range was 0.20-5.13 g/L which had linear relation with the abun-dance of characteristic ions. Thelinear equation of TBP content was Y =1.05 × 107 X+1.75 × 105 with the correlation coefficient :γ2 = 0.999. The detection limit and quantification limit were 0.000073 g/L and 0.00024 g/L for TBP ,respectively. The average recovery rate was 106.2 % -109.2 with the relative standard deviation (n=6) of 0.36% -1.70%. The practical application shows the method is suitable for the qualitative control of TBP in cementing slurry additives.
