中国工程科学
中國工程科學
중국공정과학
ENGINEERING SCIENCE
2014年
7期
84-88
,共5页
芦瑛%赵海洋%张林%侯立安
蘆瑛%趙海洋%張林%侯立安
호영%조해양%장림%후립안
氧化石墨烯%聚酰胺%混合基质膜%反渗透%耐氯性
氧化石墨烯%聚酰胺%混閤基質膜%反滲透%耐氯性
양화석묵희%취선알%혼합기질막%반삼투%내록성
GO%polyamide%mixed matrix membrane%RO%chlorine resistance
以间苯二胺(MPD)为水相单体、均苯三甲酰氯(TMC)为油相单体,氧化石墨烯(GO)作为水相添加物,采用界面聚合法,制备了GO-PA(聚酰胺)/PSF(聚砜)混合基质反渗透复合膜。采用扫描电子显微镜表征了膜形貌,考察了该膜对氯化钠的截留性能及耐氯性。结果表明,聚酰胺反渗透膜填充氧化石墨烯后,其分离性能优于聚酰胺膜,且具有较好的耐氯性。随着氧化石墨烯含量的增加,膜的通量增大,当添加量为0.005%时,膜具有最大通量,为63 L/(m2?h)。
以間苯二胺(MPD)為水相單體、均苯三甲酰氯(TMC)為油相單體,氧化石墨烯(GO)作為水相添加物,採用界麵聚閤法,製備瞭GO-PA(聚酰胺)/PSF(聚砜)混閤基質反滲透複閤膜。採用掃描電子顯微鏡錶徵瞭膜形貌,攷察瞭該膜對氯化鈉的截留性能及耐氯性。結果錶明,聚酰胺反滲透膜填充氧化石墨烯後,其分離性能優于聚酰胺膜,且具有較好的耐氯性。隨著氧化石墨烯含量的增加,膜的通量增大,噹添加量為0.005%時,膜具有最大通量,為63 L/(m2?h)。
이간분이알(MPD)위수상단체、균분삼갑선록(TMC)위유상단체,양화석묵희(GO)작위수상첨가물,채용계면취합법,제비료GO-PA(취선알)/PSF(취풍)혼합기질반삼투복합막。채용소묘전자현미경표정료막형모,고찰료해막대록화납적절류성능급내록성。결과표명,취선알반삼투막전충양화석묵희후,기분리성능우우취선알막,차구유교호적내록성。수착양화석묵희함량적증가,막적통량증대,당첨가량위0.005%시,막구유최대통량,위63 L/(m2?h)。
Graphene-oxide-(GO)-mixed-matrix-reverse-osmosis-(RO)-membranes-were-pre-pared-with-metaphenylenediamine-(MPD)-and-trimesoyl-chloride-(TMC)-by-interfacial-polymer-ization.-The-morphology-of-the-membranes-was-characterized-by-scanning-electron-microscopy-(SEM).-The-separation-performance-and-chlorine-resistance-were-also-investigated.-The-results-showed-that-owing-to-the-hydrophilicity-of-GO,the-membranes-appeared-to-be-more-hydrophil-ic-and-had-higher-pure-water-fluxes-than-the-bared-polyamide-RO-membrane-only-with-a-slight-change-of-rejection.-The-mixed-matrix-RO-membrane-of-polyamide-and-GO-showed-better-chlo-rine-resistance-than-polyamide-RO-membrane.-When-the-content-of-GO-added-in-aqueous-phase-was-0.005-wt%,the-flux-of-the-membrane-was-maximum,and-the-flux-of-the-membrane-was-63-L/(m2?h).