高等学校化学学报
高等學校化學學報
고등학교화학학보
CHEMICAL JOURNAL OF CHINESE UNIVERSITIES
2014年
8期
1799-1809
,共11页
杨光%王传明%唐萍%顾松园
楊光%王傳明%唐萍%顧鬆園
양광%왕전명%당평%고송완
对称柔性-半刚性-柔性三嵌段共聚物%自洽场理论%蠕虫状链模型%自组装%链折叠%液晶成核机理
對稱柔性-半剛性-柔性三嵌段共聚物%自洽場理論%蠕蟲狀鏈模型%自組裝%鏈摺疊%液晶成覈機理
대칭유성-반강성-유성삼감단공취물%자흡장이론%연충상련모형%자조장%련절첩%액정성핵궤리
Symmetric coil-semiflexible-coil triblock copolymer%Self-consistent field theory( SCFT)%Worm-like chain model%Self-assembly%Chain folding%Nucleation mechanism of liquid crystal
基于蠕虫状链模型和高斯链模型的自洽场理论研究了对称柔性-半刚性-柔性三嵌段共聚物在二维空间中的相行为。在设定的计算参数下得到了多种该体系的热力学平衡态相结构,包括各向同性Isotropic相、各向异性Nematic相、层状Smectic-C相、四角柱状相、斜交型冰球状相、断层型冰球状相和稻粒状结构。与刚-柔两嵌段共聚物相比,对称柔性-半刚性-柔性三嵌段共聚物更容易形成Smectic-C相。在柱状相结构中,在柔性嵌段的牵伸作用下半刚性嵌段在液晶相区中相互穿插,从而形成菱形和长方形液晶相区。当取向相互作用较强时,半刚性嵌段沿长方形液晶相区的短边方向出现2次折叠。为进一步探索高分子折叠现象产生的原因以及液晶成核机理奠定了理论基础。
基于蠕蟲狀鏈模型和高斯鏈模型的自洽場理論研究瞭對稱柔性-半剛性-柔性三嵌段共聚物在二維空間中的相行為。在設定的計算參數下得到瞭多種該體繫的熱力學平衡態相結構,包括各嚮同性Isotropic相、各嚮異性Nematic相、層狀Smectic-C相、四角柱狀相、斜交型冰毬狀相、斷層型冰毬狀相和稻粒狀結構。與剛-柔兩嵌段共聚物相比,對稱柔性-半剛性-柔性三嵌段共聚物更容易形成Smectic-C相。在柱狀相結構中,在柔性嵌段的牽伸作用下半剛性嵌段在液晶相區中相互穿插,從而形成蔆形和長方形液晶相區。噹取嚮相互作用較彊時,半剛性嵌段沿長方形液晶相區的短邊方嚮齣現2次摺疊。為進一步探索高分子摺疊現象產生的原因以及液晶成覈機理奠定瞭理論基礎。
기우연충상련모형화고사련모형적자흡장이론연구료대칭유성-반강성-유성삼감단공취물재이유공간중적상행위。재설정적계산삼수하득도료다충해체계적열역학평형태상결구,포괄각향동성Isotropic상、각향이성Nematic상、층상Smectic-C상、사각주상상、사교형빙구상상、단층형빙구상상화도립상결구。여강-유량감단공취물상비,대칭유성-반강성-유성삼감단공취물경용역형성Smectic-C상。재주상상결구중,재유성감단적견신작용하반강성감단재액정상구중상호천삽,종이형성릉형화장방형액정상구。당취향상호작용교강시,반강성감단연장방형액정상구적단변방향출현2차절첩。위진일보탐색고분자절첩현상산생적원인이급액정성핵궤리전정료이론기출。
The self-assembly of symmetric coil-semiflexible-coil triblock copolymers in 2 D space was investi-gated using self-consistent field theory(SCFT). The semiflexible block and the coil block of the copolymers were described as wormlike chain model, and Gaussian chain model, respectively. A highly accurate and effi-cient operator splitting pseudospectral algorithm combined with SPHEREPACK software package was employed to solve modified diffusion equations for the propagators of wormlike chains. The anisotropic interactions favoring the parallel alignment between semiflexible segments was described by Maier-Saupe orientational inter-actions μN , and the enthalpic interactions between coil and semiflexible segments were described by isotro-pic Flory-Huggins interactions χN . By increasing χN and volume fraction of the coil blocks, a phase dia-gram including isotropic, nematic, smectic-C, tetragonal cylinders, oblique pucks, broken lamella pucks and rice-shaped phase for symmetric coil-semiflexible-coil triblock copolymers was built. At relatively low coil frac-tions and strong interactions, semctic-C phases were readily formed because the strong chain-stretching ener-gy, which came from the highly ordered orientation of semiflexible blocks, dominates the system free energy. In the meanwhile, the stretch from two coil sides to the bridged semiflexble block results in a higher chain-stretching energy. Therefore, more smectic-C phases formed than that in biblock copolymers. The tetragonal cylinders exhibiting weak segregation were obtained in the region of coil fractions from 0.5 to 0.6 . With the increase of coil fractions and orientational interactions, hexagonal packed pucks were found. In the rhombus and rectangle liquid crystal domain, the coil-semiflexible block junctions were observed at opposite sides, therefore a cross-link conformation of the semiflexible blocks was produced. More interestingly, the semiflexi-ble chain folds twice along the short side of the rectangle liquid crystal domain of the oblique pucks at coil fraction 0.6 and broken lamella pucks at coil fraction 0.7 . Chain folding behavior increases the interfaces be-tween coils and semiflexible blocks allowing for the coils with larger fractions to gain conformational entropy. When the coil fraction is 0.8 , chain folding behavior decreases and the semiflexible blocks orient along the long side of the rectangle liquid crystal domain, forming rice-shaped phase. These simulation results are of paramount importance in rationalizing chain folding phenomena and understanding the nucleation mechanism of liquid crystals.