农业资源与环境学报
農業資源與環境學報
농업자원여배경학보
Journal of Agricultural Resources and Environment
2014年
4期
343-348
,共6页
吴东明%陈珊珊%邓晓%武春媛%李勤奋
吳東明%陳珊珊%鄧曉%武春媛%李勤奮
오동명%진산산%산효%무춘원%리근강
海南省%有机氯农药%土壤残留%生态风险
海南省%有機氯農藥%土壤殘留%生態風險
해남성%유궤록농약%토양잔류%생태풍험
Hainan Province%organochlorine pesticide%soil residues%eco-risk evaluation
采用气相色谱法检测了海南瓜菜田的33个表层土壤样品中18种有机氯(OCPs)农药残留,并对其进行污染来源分析和初步生态风险评价。结果表明:(1)土壤中的OCPs检出率为90.9%,最高残留量为17.37 ng·g-1,平均值为2.30 ng·g-1;(2)18种OCPs均有检出,六六六(HCHs)、滴滴涕(DDTs)、硫丹类农药的检出率较高,分别为63.6%、57.6%、54.5%;(3)DDTs是主要残留物质,占总OCPs残留量的54.6%,18.2%的土样可能有DDTs新的输入,土壤中HCHs主要来源于过去使用的林丹;(4)与国内其他地区土壤和国家《土壤环境质量标准》(GB 15618-1995)一级标准相比,海南省瓜菜田土壤DDTs和HCHs残留量处于较低水平,生态风险也较低。
採用氣相色譜法檢測瞭海南瓜菜田的33箇錶層土壤樣品中18種有機氯(OCPs)農藥殘留,併對其進行汙染來源分析和初步生態風險評價。結果錶明:(1)土壤中的OCPs檢齣率為90.9%,最高殘留量為17.37 ng·g-1,平均值為2.30 ng·g-1;(2)18種OCPs均有檢齣,六六六(HCHs)、滴滴涕(DDTs)、硫丹類農藥的檢齣率較高,分彆為63.6%、57.6%、54.5%;(3)DDTs是主要殘留物質,佔總OCPs殘留量的54.6%,18.2%的土樣可能有DDTs新的輸入,土壤中HCHs主要來源于過去使用的林丹;(4)與國內其他地區土壤和國傢《土壤環境質量標準》(GB 15618-1995)一級標準相比,海南省瓜菜田土壤DDTs和HCHs殘留量處于較低水平,生態風險也較低。
채용기상색보법검측료해남과채전적33개표층토양양품중18충유궤록(OCPs)농약잔류,병대기진행오염래원분석화초보생태풍험평개。결과표명:(1)토양중적OCPs검출솔위90.9%,최고잔류량위17.37 ng·g-1,평균치위2.30 ng·g-1;(2)18충OCPs균유검출,륙륙륙(HCHs)、적적체(DDTs)、류단류농약적검출솔교고,분별위63.6%、57.6%、54.5%;(3)DDTs시주요잔류물질,점총OCPs잔류량적54.6%,18.2%적토양가능유DDTs신적수입,토양중HCHs주요래원우과거사용적림단;(4)여국내기타지구토양화국가《토양배경질량표준》(GB 15618-1995)일급표준상비,해남성과채전토양DDTs화HCHs잔류량처우교저수평,생태풍험야교저。
To determine current levels of organochlorine pesticides(OCPs)and assess their sources, ecological risk in agricultural soils from typical vegetable produce areas of Hainan Province, 33 soil samples were collected and detected by the GC method. The results showed that OCPs were found in 90.9%of the collected soil samples and ranged from Not Dedected(ND)to 17.37 ng·g-1, with a mean of 2.30 ng·g-1. The DDTs、HCHs、endosulfan and endosulfan sulfate were found over 54%in the collected soil samples. Also, the DDTs were the main compo-nents, and their contribution to the residues of OCPs was over 54.6%. Analysis of the sources of contamination showed that HCHs in the area were mainly derived from lindane. DDTs, which were suspected to have recent application to 18.2%soil, were derived mainly from technical DDTs or dicofol containing DDT impurities. Comparing with various studies and the‘National Environmental Quality Standard for Soils of Chi-na’(GB 15618-1995), OCP pollutions were generally slight in present study, and the ecological risk of HCHs and DDTs residue in agricul-tural soils of Hainan Province was lower.