CAJ | 학술논문

针对CO2作为天然工质优越的制冷特性以及水合物技术在多领域的发展前景，利用水合物相平衡转折温度下压力急剧上升的特点，通过流程的创新设计，提出了一种利用CO2水合物交替生成与分解的过程来实现增压的循环系统。基于CO2复叠制冷低温级的热力学分析，结合对相平衡转折温度的考虑，通过实验表明，在套管式反应器中，0．3％（质量分数）SDS的动力学添加剂较之4％（质量分数）T HF热力学添加剂更能促进CO2水合物的生成，在-2℃、1．4 M Pa的前提下，合成时间为60 min ；在0．3％ SDS的溶液中，温度越低越易于水合物生成，其临界温度接近于-2℃，低于-2℃时，溶液结冰会堵塞管道；两套管式反应器交替运行，得到了-2℃合成、10℃分解的最佳循环温度，55 min的最短循环时间，分解后的高压CO2气体经冷凝节流后达到了-36℃的低温。
침대CO2작위천연공질우월적제랭특성이급수합물기술재다영역적발전전경，이용수합물상평형전절온도하압력급극상승적특점，통과류정적창신설계，제출료일충이용CO2수합물교체생성여분해적과정래실현증압적순배계통。기우CO2복첩제랭저온급적열역학분석，결합대상평형전절온도적고필，통과실험표명，재투관식반응기중，0．3％（질량분수）SDS적동역학첨가제교지4％（질량분수）T HF열역학첨가제경능촉진CO2수합물적생성，재-2℃、1．4 M Pa적전제하，합성시간위60 min ；재0．3％ SDS적용액중，온도월저월역우수합물생성，기림계온도접근우-2℃，저우-2℃시，용액결빙회도새관도；량투관식반응기교체운행，득도료-2℃합성、10℃분해적최가순배온도，55 min적최단순배시간，분해후적고압CO2기체경냉응절류후체도료-36℃적저온。
Based on the excellent cooling characteristics of CO 2 as a natural working substance and development prospects in the field of many hydrate technology ,using the characteristics of pressure rising sharply under the phase equilibrium transition temperature of hydrate ,through the innovation design of process ,the carbon dioxide hydrate formation and decomposition alter-nate process is used to realize the pressurization system .Based on thermodynamic analysis of car-bon dioxide level cascade refrigeration and combining with the phase equilibrium temperature ,the experiment results show that the dynamics of 0 .3w t% SDS additives is more advantageous to promote the formation of carbon dioxide hydrate in double-tube reactor compare with 4w t% T HF thermodynamics additive .The synthesis time is 60 minutes at 1 .4 MPa and -2 ℃ .In SDS solu-tion of 0 .3wt% ,lower temperature is more beneficial to the formation of hydrate ,the critical temperature is close to -2 ℃ .When it is lower than -2 ℃ ,the solution icing may block pipe . When the two sets of tube reactors are used alternately ,the optimum cyclic temperature is as fol-low s :the synthesis temperature is -2 ℃ ,the decomposition temperature is 10 ℃ ,and the shor-test cycle time is 55 minutes .The carbon dioxide gas under high pressure is decomposed by con-densation throttle to a low temperature of -36 ℃ .