CAJ | 학술논문

目的：建立固相分散萃取结合气相色谱-质谱联用法(GC/MS)快速测定葡萄酒中敌敌畏、乐果、二嗪磷等葡萄种植过程中常用43种杀虫剂、杀螨剂及杀菌剂残留量。方法样品用乙腈快速提取、氯化钠和无水硫酸镁盐析后，经 GCB粉、NH2粉和 PSA粉组合吸附剂净化， GC/MS外标法定性定量。结果43种农药在10~500μg/L范围内线性关系良好，相关系数R2在0.9851~0.9997范围内，空白添加浓度在50~200μg/kg时，其回收率在67.43%~114.74%之间，相对标准差(n=6)小于13.6%，方法的测定下限(LOD)介于1~50μg/kg 之间。结论本法简单、准确、快速，适合于葡萄酒中对43种农药残留量的检测。
목적：건립고상분산췌취결합기상색보-질보련용법(GC/MS)쾌속측정포도주중활활외、악과、이진린등포도충식과정중상용43충살충제、살만제급살균제잔류량。방법양품용을정쾌속제취、록화납화무수류산미염석후，경 GCB분、NH2분화 PSA분조합흡부제정화， GC/MS외표법정성정량。결과43충농약재10~500μg/L범위내선성관계량호，상관계수R2재0.9851~0.9997범위내，공백첨가농도재50~200μg/kg시，기회수솔재67.43%~114.74%지간，상대표준차(n=6)소우13.6%，방법적측정하한(LOD)개우1~50μg/kg 지간。결론본법간단、준학、쾌속，괄합우포도주중대43충농약잔류량적검측。
Objective A rapid analytical method was developed for the determination of 43 pesticide residues in grape wine by solid-phase dispersion with gas chromatography-mass spectrometry (GC/MS). Methods Toally 43 pesticide residues were extracted from the samples with acetonitrile, and then detected by GC/MS with external standard method after being cleaned up with three sorbents (PSA 80.0 mg、GCB 30.0 mg and NH2 30.0 mg). Results Good linearities of 10?500μg/L were obtained and correlation coefficients were 0.9851?0.9997. The recoveries of all pesticides were in the range from 67.43%to 114.74%at the spiked levels of 50, 100, and 200μg/kg in grape wine, and the relative standard deviations (RSDs) were not more than 13.6%. The limits of detection (LOD) were 1~50μg/kg. Conclusion The method could be used for the determination of 43 pesticide residues in grape wine due to its simpleness, accuracy and rapidness.