化学与生物工程
化學與生物工程
화학여생물공정
CHEMISTRY & BIOENGINEERING
2014年
8期
64-66,77
,共4页
施伟光%宫喜艳%李翠勤%王俊
施偉光%宮喜豔%李翠勤%王俊
시위광%궁희염%리취근%왕준
ASP 三元组分%原油乳液%破乳%破裂速率常数%动力学参数%单滴法
ASP 三元組分%原油乳液%破乳%破裂速率常數%動力學參數%單滴法
ASP 삼원조분%원유유액%파유%파렬속솔상수%동역학삼수%단적법
ASP three component%cru d oil emulsion%demulsification%cracking rate constant%kinetic parame-ters%single-drop method
针对单一组分及 ASP 三元组分存在的两种不同乳液体系,以排液时间 t d、半生命期 t 1/2及破裂速率常数 k为考核指标,采用单滴法研究了原油采出液中的残留组分聚合物、碱及表面活性剂的含量对破乳过程动力学参数的影响。结果表明:ASP 三元组分的残留对动力学参数的影响呈现出一定的规律,其中,聚合物是使三元复合驱油体系破乳难度增大的主要因素,在含聚合物的乳液体系中,破裂速率常数比含碱和含表面活性剂体系小一个数量级,而碱与表面活性剂对破乳的影响与这两种组分的残留量有关。
針對單一組分及 ASP 三元組分存在的兩種不同乳液體繫,以排液時間 t d、半生命期 t 1/2及破裂速率常數 k為攷覈指標,採用單滴法研究瞭原油採齣液中的殘留組分聚閤物、堿及錶麵活性劑的含量對破乳過程動力學參數的影響。結果錶明:ASP 三元組分的殘留對動力學參數的影響呈現齣一定的規律,其中,聚閤物是使三元複閤驅油體繫破乳難度增大的主要因素,在含聚閤物的乳液體繫中,破裂速率常數比含堿和含錶麵活性劑體繫小一箇數量級,而堿與錶麵活性劑對破乳的影響與這兩種組分的殘留量有關。
침대단일조분급 ASP 삼원조분존재적량충불동유액체계,이배액시간 t d、반생명기 t 1/2급파렬속솔상수 k위고핵지표,채용단적법연구료원유채출액중적잔류조분취합물、감급표면활성제적함량대파유과정동역학삼수적영향。결과표명:ASP 삼원조분적잔류대동역학삼수적영향정현출일정적규률,기중,취합물시사삼원복합구유체계파유난도증대적주요인소,재함취합물적유액체계중,파렬속솔상수비함감화함표면활성제체계소일개수량급,이감여표면활성제대파유적영향여저량충조분적잔류량유관。
To study the effect of polymer,alkali and surfactant residues in produced fluid on the kinetic pa-rameters in the process of demulsification,the drainage time(t d ),half lives(t 1/2 )and cracking rate constant(k) were measured by single-drop method in two different emulsion systems of single component and ASP three component.The results showed that:the influence of ASP three component on the kinetic parameters appeared certain regularity,and the polymer was the main factor which increased the difficulty for demulsification com-pared with alkali and surfactant.In the emulsion system containing polymer,the cracking rate constant was low-er an order magnitude compared with the system containing alkali or surfactant,while the influences of alkali and surfactant on demulsification were related to the concentration of these two components residues.