叔丁基二硅氧烷（tBu2SiX-O-SiXtBu2，X＝H，Br）的合成及表征
숙정기이규양완（tBu2SiX-O-SiXtBu2，X＝H，Br）적합성급표정
The Synthesis and Characterization of tBu-substituted Disiloxanes (tBu2 SiX-O-SiXtBu2,X = H,Br)
  • 万方数据
    杭州师范大学学报（自然科学版） 항주사범대학학보（자연과학판）
    JOURNAL OF HANGZHOU NORMAL UNIVERSITY(NATURAL SCIENCE EDITION)
    2014年 4期 341-344 ,共4页

    赵卉%徐金舟%效旭琼%李志芳

    조훼%서금주%효욱경%리지방

    二叔丁基硅醇%二叔丁基氯硅烷%大位阻%四甲基二硅氧烷 二叔丁基硅醇%二叔丁基氯硅烷%大位阻%四甲基二硅氧烷
    이숙정기규순%이숙정기록규완%대위조%사갑기이규양완
    di-tert-butyl silanol%di-tert-butyl chlorosilane%steric hindrance%tetramethyl disiloxane
    在氢化钠作用下，以二叔丁基硅醇与二叔丁基氯硅烷的反应为关键步骤，合成了具有大位阻取代的二硅氧烷化合物。反应条件温和，产率高，方法可靠。
    재경화납작용하，이이숙정기규순여이숙정기록규완적반응위관건보취，합성료구유대위조취대적이규양완화합물。반응조건온화，산솔고，방법가고。
    A new method for the synthesis of tert-butyl substituted disiloxanes was described . The products were obtained by the reaction of di-tert-butylsilanol and di-tert-butylchlorosilane in the presence of sodium hydride .The method was efficient and reliable with high yield .
    원문보기 원문다운로드 사이트로이동
저자의 최근 논문