CAJ | 학술논문

采用化学气相沉积( CVD)法,在304型不锈钢管道内壁分别沉积了TiN和TiC涂层,并采用SEM、EDS、金相显微镜和热冲击等方法对其进行了性能表征和测试。结果表明,两种涂层均匀致密, TiN 涂层厚度为7.24μm, TiC 涂层为11.52μm,且均具有良好的结合强度。为评价涂层抑制结焦效果,选用某碳氢燃料A,采取程序升温法进行超临界裂解实验,当反应管前后压差超过1 MPa时停止实验,结果表明,304空白管由于严重结焦,在650℃只运行了180 s；而TiC和TiN涂层管分别在780℃运行了275和1560 s。通过压差、产气组成和积炭微观形貌的综合分析表明,TiN、TiC涂层均呈现出优良的抑焦效果,且TiN涂层抑焦效果更优。
채용화학기상침적( CVD)법,재304형불수강관도내벽분별침적료TiN화TiC도층,병채용SEM、EDS、금상현미경화열충격등방법대기진행료성능표정화측시。결과표명,량충도층균균치밀, TiN 도층후도위7.24μm, TiC 도층위11.52μm,차균구유량호적결합강도。위평개도층억제결초효과,선용모탄경연료A,채취정서승온법진행초림계렬해실험,당반응관전후압차초과1 MPa시정지실험,결과표명,304공백관유우엄중결초,재650℃지운행료180 s；이TiC화TiN도층관분별재780℃운행료275화1560 s。통과압차、산기조성화적탄미관형모적종합분석표명,TiN、TiC도층균정현출우량적억초효과,차TiN도층억초효과경우。
In order to inhibit the metal catalytic coking, the TiN and TiC coatings were made on the inner surface of stainless steel 304 tubes by chemical vapor deposition ( CVD ) method. The coatings were characterized by means of scanning electron microscopy ( SEM) , energy-dispersive X-ray spectroscopy ( EDS) , metalloscopy and thermal shock. The results show that the thickness of TiN and TiC coatings is about 7. 24μm and 11. 52μm, respectively. And the two kinds of coatings are uniform and dense, which have a good adhesive strength. To evaluate the anti-coking effect of TiN and TiC coatings, the supercritical cracking of hydrocarbon fuel ( A ) was employed in the temperature programmed mode and the experiment was terminated when the pressure drop of reaction tube is more than 1 MPa. The results show that the experiment with the 304 blank tube is terminated in 180 s at the reaction temperature of 650℃, while the experiments with the TiN and TiC coated tubes are terminated in 275 s and 1 560 s only at 780℃, respectively. At the same time, the anti-coking effect of the coatings is evaluated by analyzing the pressure drop, gas composition and morphology of coke. It is indicated that the two kinds of coatings could inhibit coking effectively, and TiN is better than TiC.