CAJ | 학술논문

以铜试剂等为反应原料合成了4-（二（2-二乙基二硫代氨基甲酸酯基））胺基苯甲醛（ ZY3），通过 X-射线单晶衍射对其晶体结构进行了表征，并且研究了它的螯合性能。研究结果表明： ZY3属于单斜晶系，空间群为 P2（1）/n。它与重金属离子有很强的配位作用，与 Cu2＋的络合比例为1∶1，可通过分光光度法检测微量Cu2＋。
이동시제등위반응원료합성료4-（이（2-이을기이류대안기갑산지기））알기분갑철（ ZY3），통과 X-사선단정연사대기정체결구진행료표정，병차연구료타적오합성능。연구결과표명： ZY3속우단사정계，공간군위 P2（1）/n。타여중금속리자유흔강적배위작용，여 Cu2＋적락합비례위1∶1，가통과분광광도법검측미량Cu2＋。
(4 -Formylphenylazanediyl) -bis -(ethane -2,1 -diyl) -bis -diethyl -carbamodithioate (ZY3) has been synthesized by the materials of copper reagent,etc.The crystal structure of ZY3 was deter-mined by single crystal X -ray diffraction ,and its chelating property was also investigated .The results showed that the ZY3 belonged to monoclinic system,space group,P2(1)/n.It had very strong coordinating ability with heavy metal ions,the stoichiometry of Cu2+and ZY3 was estimated to be 1∶1,and it can detect trace Cu2+by spectrophotometry.