发光学报
髮光學報
발광학보
CHINESE JOURNAL OF LUMINESCENCE
2014年
7期
761-766
,共6页
毛德丰%金鹏%李维%刘贵鹏%王维颖%王占国
毛德豐%金鵬%李維%劉貴鵬%王維穎%王佔國
모덕봉%금붕%리유%류귀붕%왕유영%왕점국
发光强度%局域态%极化电场%温度%AlGaN合金
髮光彊度%跼域態%極化電場%溫度%AlGaN閤金
발광강도%국역태%겁화전장%온도%AlGaN합금
illuminant intensity%local state%polarization electric field%temperature%AlGaN alloy
通过MOVPE方法生长了不同Al组分的3块Alx Ga1-x N样品,利用稳态光谱和时间分辨光谱对其样品的光学特性进行了分析。鉴于影响氮化物发光性质的极化电场或局域态的单一机制不能充分解释我们的实验现象,提出了局域态-内部极化电场竞争的机制。通过对实验数据的分析,得出如下重要结论:样品PL峰位蓝移的温度起点基本对应于局域态和极化电场起作用的交替点,PL峰位发生蓝移的温度起点与光强-温度曲线的斜率出现明显变化的温度点一致;随着温度的升高,若AlGaN合金样品中PL峰位存在二次蓝移,则说明样品中电场分布不均匀。
通過MOVPE方法生長瞭不同Al組分的3塊Alx Ga1-x N樣品,利用穩態光譜和時間分辨光譜對其樣品的光學特性進行瞭分析。鑒于影響氮化物髮光性質的極化電場或跼域態的單一機製不能充分解釋我們的實驗現象,提齣瞭跼域態-內部極化電場競爭的機製。通過對實驗數據的分析,得齣如下重要結論:樣品PL峰位藍移的溫度起點基本對應于跼域態和極化電場起作用的交替點,PL峰位髮生藍移的溫度起點與光彊-溫度麯線的斜率齣現明顯變化的溫度點一緻;隨著溫度的升高,若AlGaN閤金樣品中PL峰位存在二次藍移,則說明樣品中電場分佈不均勻。
통과MOVPE방법생장료불동Al조분적3괴Alx Ga1-x N양품,이용은태광보화시간분변광보대기양품적광학특성진행료분석。감우영향담화물발광성질적겁화전장혹국역태적단일궤제불능충분해석아문적실험현상,제출료국역태-내부겁화전장경쟁적궤제。통과대실험수거적분석,득출여하중요결론:양품PL봉위람이적온도기점기본대응우국역태화겁화전장기작용적교체점,PL봉위발생람이적온도기점여광강-온도곡선적사솔출현명현변화적온도점일치;수착온도적승고,약AlGaN합금양품중PL봉위존재이차람이,칙설명양품중전장분포불균균。
Three Alx Ga1-x N samples were grown by metal organic chemical vapor phase deposition ( MOCVD) , and their optical properties were analyzed by the steady-state and time-resolved photo-luminescence ( PL) techniques. In view of the fact that the experimental phenomena can't be fully explained by a single mechanism of polarization electric field or that of local state, which remarkably influence luminescent properties of nitrids, the competition mechanism between local state and inter-nal polarization electric field was proposed. By analyzing the experimental data, two crucial conclu-sions are drawn. First, the temperature starting point of PL peak blue-shift basically corresponds to the shift point between the effect of local state and the effect of polarization electric field. The tem-perature starting point of PL peak blue-shift is well consistent with the temperature point where the slope of illuminant intensity-temperature curve changes significantly. Then, there is non-uniform po-larization electric field distribution in the sample if the PL peak has two blue-shifts with the tempera-ture increasing in AlGaN alloy.