CAJ | 학술논문

最近，碱性聚合物电解质膜燃料电池(APEMFC)因具有电极反应动力学快以及不依赖于贵金属铂催化剂等诸多优点而成为一个热门话题。作为其中一个关键部件，碱性聚合物电解质膜直接影响燃料电池的性能和成本。然而，迄今为止，仍然没有令人满意的碱性电解质膜材料。为此，大量研究被开展和报道。本文综述了近三年内文献中关于燃料电池碱性聚合物电解质膜的最新研究进展：包括各种各样的合成策略，构效关系，水管理以及非原位或原位稳定性测试等等。尤其是一些新的金属离子基阴离子交换膜和冠醚基阴离子交换膜首次被提及和评论。此外，还进一步预测了将来的发展趋势。
최근，감성취합물전해질막연료전지(APEMFC)인구유전겁반응동역학쾌이급불의뢰우귀금속박최화제등제다우점이성위일개열문화제。작위기중일개관건부건，감성취합물전해질막직접영향연료전지적성능화성본。연이，흘금위지，잉연몰유령인만의적감성전해질막재료。위차，대량연구피개전화보도。본문종술료근삼년내문헌중관우연료전지감성취합물전해질막적최신연구진전：포괄각충각양적합성책략，구효관계，수관리이급비원위혹원위은정성측시등등。우기시일사신적금속리자기음리자교환막화관미기음리자교환막수차피제급화평론。차외，환진일보예측료장래적발전추세。
Alkaline polymer electrolyte membrane fuel cell (APEMFC) has received much recent attention, primarily motivated by their fast dynamics and independence on expensive Pt-based electrocatalysts. As one of vital components of APEMFC, the alkaline polymer membrane directly influences their performance and cost. However, to date, no alkaline membrane has provided a satisfactory benchmark for use in APEMFC. Therefore, intensive efforts have been made to pursue desirable polymer membrane materials. In this article, the research progress over the last 3 years on state-of-the-art alkaline polymer electrolyte membranes for APEMFC is reviewed, including various synthesis strategies, structure-property relationships, water management, and ex situ and in situ stability tests. More specifically, some new metal-cation-based anion exchange membranes, such as ruthenium-complex-based and crown-ether-based anion exchange membranes, are commented on for the first time. Furthermore, future development prospects are also predicted.