功能材料
功能材料
공능재료
JOURNAL OF FUNCTIONAL MATERIALS
2014年
16期
16052-16055
,共4页
俞平%黄建业%刘伟庭%顾春欣%傅新%Paolo Dario
俞平%黃建業%劉偉庭%顧春訢%傅新%Paolo Dario
유평%황건업%류위정%고춘흔%부신%Paolo Dario
定向纳米纤维%TPU/MWNTs%静电纺丝%压阻
定嚮納米纖維%TPU/MWNTs%靜電紡絲%壓阻
정향납미섬유%TPU/MWNTs%정전방사%압조
oriented nanofibers%TPU/MWNTs%electrospinning%piezoresistive property
利用静电纺丝技术制备了热塑性聚氨酯/多壁碳纳米管(TPU/MWNTs)复合纳米纤维,并通过平行板接收装置实现纤维的定向排布。测试了纤维压阻敏感性随MWNTs含量的变化规律,与浇注法制备的TPU/MWNTs膜的压阻敏感性进行对比分析,结果表明MWNTs含量仅为2.91%(质量分数)时,纤维就表现出了最佳的压阻特性(Gauge factor≈11.4),比同质量分数下膜的压阻特性(Gauge factor≈2.6)有较大的提高,同时在8%的拉伸应变内电阻的相对变化量与应变值维持良好的线性关系,线性度优于复合膜。
利用靜電紡絲技術製備瞭熱塑性聚氨酯/多壁碳納米管(TPU/MWNTs)複閤納米纖維,併通過平行闆接收裝置實現纖維的定嚮排佈。測試瞭纖維壓阻敏感性隨MWNTs含量的變化規律,與澆註法製備的TPU/MWNTs膜的壓阻敏感性進行對比分析,結果錶明MWNTs含量僅為2.91%(質量分數)時,纖維就錶現齣瞭最佳的壓阻特性(Gauge factor≈11.4),比同質量分數下膜的壓阻特性(Gauge factor≈2.6)有較大的提高,同時在8%的拉伸應變內電阻的相對變化量與應變值維持良好的線性關繫,線性度優于複閤膜。
이용정전방사기술제비료열소성취안지/다벽탄납미관(TPU/MWNTs)복합납미섬유,병통과평행판접수장치실현섬유적정향배포。측시료섬유압조민감성수MWNTs함량적변화규률,여요주법제비적TPU/MWNTs막적압조민감성진행대비분석,결과표명MWNTs함량부위2.91%(질량분수)시,섬유취표현출료최가적압조특성(Gauge factor≈11.4),비동질량분수하막적압조특성(Gauge factor≈2.6)유교대적제고,동시재8%적랍신응변내전조적상대변화량여응변치유지량호적선성관계,선성도우우복합막。
Electrospinning was applied to produce oriented nanofibers consisting of thermal-plastic polyurethane (TPU)and multi-walled nanotubes (MWNTs)composites.Comparison TPU/MWNTs films were made through casting technology.The relationship between relative changes in resistance versus tensile strain has been analyzed.The maximum gauge factor (≈1 1 .4)of fibers was reached when the mass fraction of MWNTs was 1.84%.At the same mass fraction,gauge factor of films was only 2.6.The piezoresistive response of fi-bers was linear within 8% of tensile strain which was better than that of TPU/MWNTs films.