功能材料
功能材料
공능재료
JOURNAL OF FUNCTIONAL MATERIALS
2014年
16期
16018-16021
,共4页
王衍行%何坤%祖成奎%张瑞%韩滨%陈江
王衍行%何坤%祖成奎%張瑞%韓濱%陳江
왕연행%하곤%조성규%장서%한빈%진강
硼硅玻璃%离子交换%光学性能%透过率%折射率
硼硅玻璃%離子交換%光學性能%透過率%摺射率
붕규파리%리자교환%광학성능%투과솔%절사솔
borosilicate glass%ion exchange%optical property%transmission%refractive index
利用电子探针、分光光度计和干涉显微镜等手段,研究了离子交换对硼硅玻璃光学性能的影响。结果表明,离子交换后硼硅玻璃的 K+含量沿玻璃厚度方向逐渐降低。当交换时间≤8h时,交换层厚度与交换时间呈线性增加;当交换时间>8h 时,交换层厚度增加缓慢。离子交换增强后,硼硅玻璃的透过率小幅度下降,但仍保持在91%以上。离子交换后硼硅玻璃中折射率从玻璃表面向内部呈指数降低,这与 K+离子在玻璃中的不均匀分布相关。综合考虑应用器件对强度和光学均匀性要求,硼硅玻璃的离子交换时间应不大于3h。
利用電子探針、分光光度計和榦涉顯微鏡等手段,研究瞭離子交換對硼硅玻璃光學性能的影響。結果錶明,離子交換後硼硅玻璃的 K+含量沿玻璃厚度方嚮逐漸降低。噹交換時間≤8h時,交換層厚度與交換時間呈線性增加;噹交換時間>8h 時,交換層厚度增加緩慢。離子交換增彊後,硼硅玻璃的透過率小幅度下降,但仍保持在91%以上。離子交換後硼硅玻璃中摺射率從玻璃錶麵嚮內部呈指數降低,這與 K+離子在玻璃中的不均勻分佈相關。綜閤攷慮應用器件對彊度和光學均勻性要求,硼硅玻璃的離子交換時間應不大于3h。
이용전자탐침、분광광도계화간섭현미경등수단,연구료리자교환대붕규파리광학성능적영향。결과표명,리자교환후붕규파리적 K+함량연파리후도방향축점강저。당교환시간≤8h시,교환층후도여교환시간정선성증가;당교환시간>8h 시,교환층후도증가완만。리자교환증강후,붕규파리적투과솔소폭도하강,단잉보지재91%이상。리자교환후붕규파리중절사솔종파리표면향내부정지수강저,저여 K+리자재파리중적불균균분포상관。종합고필응용기건대강도화광학균균성요구,붕규파리적리자교환시간응불대우3h。
The effect of ion exchange on optical properties of borosilicate glass was studied by means of EPMA, spectrophotometer and interference microscope.In the surface of borosilicate glass after ion exchange treat-ment,content of K+ gradually reduce along the thickness direction.When ion exchange time was less than 8 h, thickness of exchange layer increases linearly.However,thickness of exchange layer increases slowly if ion ex-change treatment goes on.Transmission of borosilicate glass after ion exchange treatment decreases slightly compared with that of original glass,but it was still higher than 9 1%.Refractive index of borosilicate glass af-ter ion exchange treatment decreases exponentially from the surface to the inside,which was related with distri-bution of K+ in borosilicate glass.When ion exchange time was less than 3 h,borosilicate glass will possess ex-cellent mechanical and optical properties simultaneously.